{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362825893342887168.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/hc.20291"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fhc.20291"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/hc.20291"}},{"identifier":{"@type":"DOI","@value":"10.1002/chin.200733164"}}],"dc:title":[{"@value":"A new method for the synthesis of dinaphtho[1,2‐<i>b</i>;2′,1′‐<i>d</i>]thiophenes and selenophenes"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Naphthalene‐1‐sulfonic acid dimethylamides were treated with <jats:italic>n</jats:italic>‐BuLi and elemental sulfur or selenium to afford dinaphtho[1,2‐<jats:italic>b</jats:italic>:2′,1′‐<jats:italic>d</jats:italic>]thiophenes and selenophenes, respectively. This is the first example of making two CS/Se bonds and a CC bond in a single step at room temperature and also demonstrates a useful method for the synthesis of both thiophenes and selenophenes on naphthalene. In the case of the reactions of elemental selenium, diselenides were also obtained along with dinaphtho[1,2‐<jats:italic>b</jats:italic>:2′,1′‐<jats:italic>d</jats:italic>]selenophenes. The structure of dinaphtho[1,2‐<jats:italic>b</jats:italic>:′,1′‐<jats:italic>d</jats:italic>]thiophene was characterized by X‐ray crystallography as a representative molecule. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:239–248, 2007; Published online in Wiley InterScience (<jats:ext-link xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"http://www.interscience.wiley.com\">www.interscience.wiley.com</jats:ext-link>). DOI 10.1002/hc.20291</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382825893342887171","@type":"Researcher","foaf:name":[{"@value":"Ashraful Alam"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825893342887170","@type":"Researcher","foaf:name":[{"@value":"Hidetoshi Ohta"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825893342887168","@type":"Researcher","foaf:name":[{"@value":"Tatsuya Yamamoto"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825893342887172","@type":"Researcher","foaf:name":[{"@value":"Satoshi Ogawa"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825893342887169","@type":"Researcher","foaf:name":[{"@value":"Ryu Sato"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"10427163"},{"@type":"EISSN","@value":"10981071"},{"@type":"PISSN","@value":"09317597"},{"@type":"EISSN","@value":"15222667"}],"prism:publicationName":[{"@value":"Heteroatom Chemistry"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2007-04","prism:volume":"18","prism:number":"3","prism:startingPage":"239","prism:endingPage":"248"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fhc.20291"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/hc.20291"}],"createdAt":"2007-04-09","modifiedAt":"2023-10-13","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002219111532672","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Convenient Synthesis of Dibenzo[<i>a</i>,<i>h</i>]anthracenes and Picenes via C–H Arylation of Acetophenones with Arenediboronates"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708590413696","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Effects of chalcogen atom substitution on the optoelectronic and charge-transport properties in picene-type π-systems"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183132946048","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Dinaphtho[1,2-<i>b</i>:2′,1′-<i>d</i>]chalcogenophenes: Comprehensive Investigation of the Effect of the Chalcogen Atoms in the Phenacene-Type π-Electronic Cores"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183183336832","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of Optically Pure 3,3′-Diaryl Binaphthyl Disulfonic Acids <i>via</i> Stepwise N–S Bond Cleavage"}]},{"@id":"https://cir.nii.ac.jp/crid/1881428068074824192","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 601484: Experimental Crystal Structure Determination"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/hc.20291"},{"@type":"OPENAIRE","@value":"doi_dedup___::c3880b64813ff10e07a9c99381d0d9e1"},{"@type":"CROSSREF","@value":"10.1039/c7cc01292f_references_DOI_XrfCYss09GtLB5j6HFt6NPeOhUr"},{"@type":"CROSSREF","@value":"10.1021/cm303376g_references_DOI_XrfCYss09GtLB5j6HFt6NPeOhUr"},{"@type":"CROSSREF","@value":"10.1246/cl.2011.300_references_DOI_XrfCYss09GtLB5j6HFt6NPeOhUr"},{"@type":"CROSSREF","@value":"10.1021/jo401848z_references_DOI_XrfCYss09GtLB5j6HFt6NPeOhUr"}]}