{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362825893592690048.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/anie.201706378"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201706378"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201706378"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.201706378"}}],"dc:title":[{"@value":"Palladium‐Catalyzed Carbon–Fluorine and Carbon–Hydrogen Bond Alumination of Fluoroarenes and Heteroarenes"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Through serendipitous discovery, a palladium bis(phosphine) complex was identified as a catalyst for the selective transformation of sp<jats:sup>2</jats:sup>C−F and sp<jats:sup>2</jats:sup>C−H bonds of fluoroarenes and heteroarenes to sp<jats:sup>2</jats:sup>C−Al bonds (19 examples, 1 mol % Pd loading). The carbon–fluorine bond functionalization reaction is highly selective for the formation of organoaluminium products in preference to hydrodefluorination products (selectivity=4.4:1 to 27:1). Evidence is presented for a tandem catalytic process in which hydrodefluorination is followed by sp<jats:sup>2</jats:sup>C−H alumination.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382825893592690049","@type":"Researcher","foaf:name":[{"@value":"Wenyi Chen"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Imperial College London  South Kensington London SW7 2AZ UK"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825893592690048","@type":"Researcher","foaf:name":[{"@value":"Thomas N. Hooper"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Imperial College London  South Kensington London SW7 2AZ UK"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825893592690176","@type":"Researcher","foaf:name":[{"@value":"Jamues Ng"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Imperial College London  South Kensington London SW7 2AZ UK"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825893592690178","@type":"Researcher","foaf:name":[{"@value":"Andrew J. P. White"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Imperial College London  South Kensington London SW7 2AZ UK"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825893592690177","@type":"Researcher","foaf:name":[{"@value":"Mark R. Crimmin"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Imperial College London  South Kensington London SW7 2AZ UK"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14337851"},{"@type":"EISSN","@value":"15213773"}],"prism:publicationName":[{"@value":"Angewandte Chemie International Edition"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2017-08-30","prism:volume":"56","prism:number":"41","prism:startingPage":"12687","prism:endingPage":"12691"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201706378"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201706378"},{"@id":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.201706378"}],"createdAt":"2017-08-15","modifiedAt":"2023-09-03","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050282813449595136","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Ring-expanding and ring-opening transformations of benzofurans and indoles with introducing heteroatoms"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/anie.201706378"},{"@type":"CROSSREF","@value":"10.1246/cl.190393_references_DOI_Ok54VPROVVWwoYKbaNT8evYcVPx"}]}