{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362825893635752448.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/jp201017e"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/jp201017e"}}],"dc:title":[{"@value":"Controlling Particle Size and Structural Properties of Mesoporous Silica Nanoparticles Using the Taguchi Method"}],"description":[{"notation":[{"@value":"The Taguchi method, a statistical design with an L8 orthogonal array, was adopted to optimize the synthetic conditions of mesoporous silica nanoparticles (MSNs) with respect to particle size and structural properties. The amount of the silica source (i.e., tetraethoxysilane), pH value, and reaction time were selected as significant parameters affecting the size and structural properties of the synthesized MSNs. Particle sizes ranging from 17 to 247 nm were successfully controlled by the Taguchi method, and the statistical data based on experimental results indicated that the pH value of the silica/surfactant precursor solution had a greater influence (57%) on particle size than did reaction time and the TEOS amount (29% and 13%, respectively). The effects of individual parameters on particle size and structural properties, such as surface area and structural ordering, were also investigated by changing one parameter at a time. We concluded that the pH value strongly affected mesostructural ordering and pa..."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382825893635752448","@type":"Researcher","foaf:name":[{"@value":"Ya-Dong Chiang"}],"jpcoar:affiliationName":[{"@value":"Department of Chemical Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825893635752576","@type":"Researcher","foaf:name":[{"@value":"Hong-Yuan Lian"}],"jpcoar:affiliationName":[{"@value":"Department of Chemical Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825893635752451","@type":"Researcher","foaf:name":[{"@value":"Sin-Yen Leo"}],"jpcoar:affiliationName":[{"@value":"Department of Chemical Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825893635752452","@type":"Researcher","foaf:name":[{"@value":"Shy-Guey Wang"}],"jpcoar:affiliationName":[{"@value":"Department of Chemical Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825893635752449","@type":"Researcher","foaf:name":[{"@value":"Yusuke Yamauchi"}],"jpcoar:affiliationName":[{"@value":"World Premier International (WPI) Research Center for Materials Nanoarchitectonics, National Institute for Materials Science, 1-1 Namiki, Tsukuba 305-0044, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825893635752450","@type":"Researcher","foaf:name":[{"@value":"Kevin C.-W. Wu"}],"jpcoar:affiliationName":[{"@value":"Department of Chemical Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan"},{"@value":"Division of Medical Engineering Research, National Health Research Institutes, 35 Keyan Road, Zhunan, Miaoli County 350, Taiwan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"19327447"},{"@type":"EISSN","@value":"19327455"}],"prism:publicationName":[{"@value":"The Journal of Physical Chemistry C"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2011-06-17","prism:volume":"115","prism:number":"27","prism:startingPage":"13158","prism:endingPage":"13165"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/jp201017e"}],"createdAt":"2011-06-08","modifiedAt":"2023-04-15","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Surfaces","dc:title":"Surfaces"},{"@id":"https://cir.nii.ac.jp/all?q=Coatings%20and%20Films","dc:title":"Coatings and Films"},{"@id":"https://cir.nii.ac.jp/all?q=General%20Energy","dc:title":"General Energy"},{"@id":"https://cir.nii.ac.jp/all?q=Electronic","dc:title":"Electronic"},{"@id":"https://cir.nii.ac.jp/all?q=Optical%20and%20Magnetic%20Materials","dc:title":"Optical and Magnetic Materials"},{"@id":"https://cir.nii.ac.jp/all?q=Physical%20and%20Theoretical%20Chemistry","dc:title":"Physical and Theoretical Chemistry"},{"@id":"https://cir.nii.ac.jp/all?q=620","dc:title":"620"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360285705050759040","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Effective Use of Alkoxysilanes with Different Hydrolysis Rates for Particle Size Control of Aqueous Colloidal Mesostructured and Mesoporous Silica Nanoparticles by the Seed‐Growth Method"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565164621059200","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Evaporation‐Induced Coating of Hydrous Ruthenium Oxide on Mesoporous Silica Nanoparticles to Develop High‐Performance Supercapacitors"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567182312512000","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Hard-templating synthesis of macroporous platinum microballs (MPtM)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848657302378240","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"An integrated function system using metal nanoparticle@mesoporous silica@metal-organic framework hybrids"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658068258176","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Sub-2 nm Single-Crystal Pt Nanoparticles via Sputtering onto a Liquid Polymer"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679119907584","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Colloidal Mesoporous Silica Nanoparticles"},{"@value":"Accounts for Nanospace Materials : The Chemical Society of Japan Award for 2014 : Colloidal Mesoporous Silica Nanoparticles"},{"@value":"ChemInform Abstract: Colloidal Mesoporous Silica Nanoparticles"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679566697472","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Novel Inorganic Gatekeeper Strategy for Obtaining Controlled Release in Mesoporous Silica Nanoparticles"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1021/jp201017e"},{"@type":"OPENAIRE","@value":"doi_dedup___::ed23ccd6d7e9067328d2e9e598e1cd92"},{"@type":"CROSSREF","@value":"10.1002/cnma.201500010_references_DOI_SdRxsIDZQLTi1vDgP54bQZ5h6Lk"},{"@type":"CROSSREF","@value":"10.1002/smll.201202786_references_DOI_SdRxsIDZQLTi1vDgP54bQZ5h6Lk"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20150420_references_DOI_SdRxsIDZQLTi1vDgP54bQZ5h6Lk"},{"@type":"CROSSREF","@value":"10.1016/j.micromeso.2017.02.074_references_DOI_SdRxsIDZQLTi1vDgP54bQZ5h6Lk"},{"@type":"CROSSREF","@value":"10.1021/acs.langmuir.7b04274_references_DOI_SdRxsIDZQLTi1vDgP54bQZ5h6Lk"},{"@type":"CROSSREF","@value":"10.1016/j.matlet.2015.11.002_references_DOI_SdRxsIDZQLTi1vDgP54bQZ5h6Lk"},{"@type":"CROSSREF","@value":"10.1246/cl.140142_references_DOI_SdRxsIDZQLTi1vDgP54bQZ5h6Lk"}]}