{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362825894233704064.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/j.synthmet.2009.01.025"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0379677909000368?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0379677909000368?httpAccept=text/plain"}}],"dc:title":[{"@value":"Densely packed organic nanocrystals ultrathin film using a liquid–liquid interface"}],"description":[{"notation":[{"@value":"We report a fabrication of densely packed polydiacetylene nanocrystal film using a liquid–liquid interface. Polydiacetylene (pDCHD) nanocrystals was dispersed into water solution by reprecipitation method from a good solvent. Then, hexane was added to the water dispersion to create the liquid–liquid interface. pDCHD nanocrystals were assembled at the interface, when ethanol was added to the pDCHD water dispersion–hexane solution. The assembled film was transferred onto a solid substrate and the film morphology was observed by scanning electron microscope (SEM). With addition of 10 vol% of ethanol to 2.5 mM of pDCHD water dispersion–hexane solution, a densely packed pDCHD film is fabricated. Optical and electrical properties of the pDCHD film are discussed by UV–vis spectroscopy and current–voltage measurement."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382825894233704065","@type":"Researcher","foaf:name":[{"@value":"J. Matsui"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825894233704066","@type":"Researcher","foaf:name":[{"@value":"T. Shibata"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825894233704070","@type":"Researcher","foaf:name":[{"@value":"K. Yamamoto"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825894233704069","@type":"Researcher","foaf:name":[{"@value":"T. Yokoyama"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825894233704064","@type":"Researcher","foaf:name":[{"@value":"A. Masuhara"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825894233704071","@type":"Researcher","foaf:name":[{"@value":"H. Kasai"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825894233704068","@type":"Researcher","foaf:name":[{"@value":"H. Oikawa"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825894233704067","@type":"Researcher","foaf:name":[{"@value":"T. Miyashita"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"03796779"}],"prism:publicationName":[{"@value":"Synthetic Metals"}],"dc:publisher":[{"@value":"Elsevier BV"}],"prism:publicationDate":"2009-05","prism:volume":"159","prism:number":"9-10","prism:startingPage":"847","prism:endingPage":"850"},"reviewed":"false","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/","https://www.elsevier.com/legal/tdmrep-license"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:S0379677909000368?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:S0379677909000368?httpAccept=text/plain"}],"createdAt":"2009-02-13","modifiedAt":"2025-10-08","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360846644035771008","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Formation of Thin Films of Densely Packed [60]Fullerene–Diaminoethane Adduct Microparticles at a Liquid/Liquid Interface and Their Photoelectrochemical Applications"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848659209952640","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"C<sub>60</sub> nanocrystals thin film with controlled density"}]},{"@id":"https://cir.nii.ac.jp/crid/2051996266980341248","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Development of fullerene thin-film assemblies and fullerene-diamine adducts towards practical nanocarbon-based electronic materials"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1016/j.synthmet.2009.01.025"},{"@type":"OPENAIRE","@value":"doi_dedup___::1126abc75915eba968938830afe6bbf7"},{"@type":"CROSSREF","@value":"10.1246/cl.141153_references_DOI_F68jOXUjJXbhwnPxnUp27qqwY62"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20190079_references_DOI_F68jOXUjJXbhwnPxnUp27qqwY62"},{"@type":"CROSSREF","@value":"10.1080/15421406.2015.1096494_references_DOI_F68jOXUjJXbhwnPxnUp27qqwY62"}]}