{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362825894379664640.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/chem.201405654"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.201405654"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201405654"}}],"dc:title":[{"@value":"Selective and Scalable Synthesis of Trifluoromethanesulfenamides and Fluorinated Unsymmetrical Disulfides using a Shelf‐Stable Electrophilic SCF<sub>3</sub> Reagent"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>The chemoselective trifluoromethylthiolation of nitrogen nucleophiles and thiols using <jats:italic>N</jats:italic>‐(trifluoromethylthio)phthalimide under mild, metal‐free conditions is described. A series of trifluoromethanesulfenamides and unsymmetrical disulfides is prepared from the corresponding aliphatic and aromatic amines and thiols in good yields. The reactions are operationally simple and tolerate a wide variety of functional groups. Trifluoromethanesulfenamides and disulfides belong to interesting classes of organic molecules which possess remarkable properties for medicinal and agrochemical applications.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382825894379664640","@type":"Researcher","foaf:name":[{"@value":"Roman Pluta"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825894379664641","@type":"Researcher","foaf:name":[{"@value":"Magnus Rueping"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"09476539"},{"@type":"EISSN","@value":"15213765"}],"prism:publicationName":[{"@value":"Chemistry – A European Journal"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2014-11-07","prism:volume":"20","prism:number":"52","prism:startingPage":"17315","prism:endingPage":"17318"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.201405654"},{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201405654"}],"createdAt":"2014-11-07","modifiedAt":"2025-10-12","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360865814751938944","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Amination of <i>N</i>-(Organodithio)phthalimides for the Modular Synthesis of Aminodisulfides"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204142494208","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of Shelf-Stable Reagents for Fluoro-Functionalization Reactions"},{"@value":"Award Accounts : The Chemical Society of Japan Award for Creative Work for 2014 : Development of Shelf-Stable Reagents for Fluoro-Functionalization Reactions"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/chem.201405654"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20160223_references_DOI_HH2xRGQbGdmRepvM3IadgmyjdKs"},{"@type":"CROSSREF","@value":"10.1021/acs.orglett.3c03419_references_DOI_HH2xRGQbGdmRepvM3IadgmyjdKs"}]}