{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362825894513838336.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1126/science.aai8611"}},{"identifier":{"@type":"URI","@value":"https://www.science.org/doi/pdf/10.1126/science.aai8611"}}],"dc:title":[{"@value":"A general, modular method for the catalytic asymmetric synthesis of alkylboronate esters"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Crafting chiral boron building blocks</jats:title>\n          <jats:p>\n            Carbon-boron bonds are easily transformed into a wide variety of C–C, C–N, and C–O bonds. With that flexibility in mind, Schmidt\n            <jats:italic>et al.</jats:italic>\n            show that nickel complexes can catalyze asymmetric alkylation of carbon centers adjacent to boron. This protocol creates chiral alkylboronates that function as stable precursors to numerous complex molecules. The reaction proceeds in stereo-convergent fashion—forming a single product from either mirror image of the α-haloboronate reagent. Successive reactions can also create chains of adjacent chiral alkyl centers with stereochemistry set by the configuration of the ligand bound to nickel.\n          </jats:p>\n          <jats:p>\n            <jats:italic>Science</jats:italic>\n            , this issue p.\n            <jats:related-article xmlns:xlink=\"http://www.w3.org/1999/xlink\" ext-link-type=\"doi\" issue=\"6317\" page=\"1265\" related-article-type=\"in-this-issue\" vol=\"354\" xlink:href=\"10.1126/science.aai8611\">1265</jats:related-article>\n          </jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382825894513838338","@type":"Researcher","foaf:name":[{"@value":"Jens Schmidt"}],"jpcoar:affiliationName":[{"@value":"Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA."}]},{"@id":"https://cir.nii.ac.jp/crid/1382825894513838336","@type":"Researcher","foaf:name":[{"@value":"Junwon Choi"}],"jpcoar:affiliationName":[{"@value":"Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA."}]},{"@id":"https://cir.nii.ac.jp/crid/1382825894513838340","@type":"Researcher","foaf:name":[{"@value":"Albert Tianxiang Liu"}],"jpcoar:affiliationName":[{"@value":"Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA."}]},{"@id":"https://cir.nii.ac.jp/crid/1382825894513838337","@type":"Researcher","foaf:name":[{"@value":"Martin Slusarczyk"}],"jpcoar:affiliationName":[{"@value":"Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA."}]},{"@id":"https://cir.nii.ac.jp/crid/1382825894513838339","@type":"Researcher","foaf:name":[{"@value":"Gregory C. Fu"}],"jpcoar:affiliationName":[{"@value":"Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA."}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00368075"},{"@type":"EISSN","@value":"10959203"}],"prism:publicationName":[{"@value":"Science"}],"dc:publisher":[{"@value":"American Association for the Advancement of Science (AAAS)"}],"prism:publicationDate":"2016-12-09","prism:volume":"354","prism:number":"6317","prism:startingPage":"1265","prism:endingPage":"1269"},"reviewed":"false","url":[{"@id":"https://www.science.org/doi/pdf/10.1126/science.aai8611"}],"createdAt":"2016-12-08","modifiedAt":"2024-01-15","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360283689402587904","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Copper(I)‐Catalyzed Enantioselective Nucleophilic Borylation of Aliphatic Ketones: Synthesis of Enantioenriched Chiral Tertiary α‐Hydroxyboronates"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708606389248","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Copper(<scp>i</scp>)-catalysed stereoselective debromoborylation of aliphatic 1,1-dibromo-1-alkenes with bis(pinacolato)diboron"}]},{"@id":"https://cir.nii.ac.jp/crid/1360298763266055424","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Copper(I)‐Catalyzed Enantioconvergent Borylation of Racemic Benzyl Chlorides Enabled by Quadrant‐by‐Quadrant Structure Modification of Chiral Bisphosphine Ligands"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848664438754816","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Ni/Co-Catalyzed Homo-Coupling of Alkyl Tosylates"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1126/science.aai8611"},{"@type":"CROSSREF","@value":"10.1002/anie.201702826_references_DOI_TtezwMmHIDZC8Q5nMliP30lxTZK"},{"@type":"CROSSREF","@value":"10.1039/c8ob01778f_references_DOI_TtezwMmHIDZC8Q5nMliP30lxTZK"},{"@type":"CROSSREF","@value":"10.1002/anie.201906011_references_DOI_TtezwMmHIDZC8Q5nMliP30lxTZK"},{"@type":"CROSSREF","@value":"10.3390/molecules24081458_references_DOI_TtezwMmHIDZC8Q5nMliP30lxTZK"}]}