{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362825895164990976.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/ange.201709762"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fange.201709762"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201709762"}}],"dc:title":[{"@value":"Divergent Total Syntheses of (−)‐Daphnilongeranin B and (−)‐Daphenylline"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>(−)‐Daphnilongeranin B and (−)‐daphenylline are two hexacyclic <jats:italic>Daphniphyllum</jats:italic> alkaloids, each containing a complex cagelike backbone. Described herein are the first asymmetric total synthesis of (−)‐daphnilongeranin B and a bioinspired synthesis of (−)‐daphenylline with an unusual E ring embedded in a cagelike framework. The key features include an intermolecular [3+2] cycloaddition, a late‐stage aldol cyclization to install the F ring of daphnilongeranin B, and a bioinspired cationic rearrangement leading to the tetrasubstituted benzene ring of daphenylline.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382825895164990978","@type":"Researcher","foaf:name":[{"@value":"Xiaoming Chen"}],"jpcoar:affiliationName":[{"@value":"Shenzhen Engineering Laboratory of Nano Drug Slow Release Key Laboratory of Chemical Genomics Shenzhen Graduate School of Peking University  Shenzhen 518055 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380298341342353920","@type":"Researcher","foaf:name":[{"@value":"Hai‐Jun Zhang"}],"jpcoar:affiliationName":[{"@value":"Shenzhen Engineering Laboratory of Nano Drug Slow Release Key Laboratory of Chemical Genomics Shenzhen Graduate School of Peking University  Shenzhen 518055 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895164990976","@type":"Researcher","foaf:name":[{"@value":"Xinkan Yang"}],"jpcoar:affiliationName":[{"@value":"The State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering Lanzhou University  222 Tianshui South Road Lanzhou 730000 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895164990983","@type":"Researcher","foaf:name":[{"@value":"Houqiang Lv"}],"jpcoar:affiliationName":[{"@value":"The State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering Lanzhou University  222 Tianshui South Road Lanzhou 730000 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895164990982","@type":"Researcher","foaf:name":[{"@value":"Xiaoru Shao"}],"jpcoar:affiliationName":[{"@value":"Shenzhen Engineering Laboratory of Nano Drug Slow Release Key Laboratory of Chemical Genomics Shenzhen Graduate School of Peking University  Shenzhen 518055 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895164990979","@type":"Researcher","foaf:name":[{"@value":"Cheng Tao"}],"jpcoar:affiliationName":[{"@value":"The State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering Lanzhou University  222 Tianshui South Road Lanzhou 730000 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895164990985","@type":"Researcher","foaf:name":[{"@value":"Huifei Wang"}],"jpcoar:affiliationName":[{"@value":"Shenzhen Engineering Laboratory of Nano Drug Slow Release Key Laboratory of Chemical Genomics Shenzhen Graduate School of Peking University  Shenzhen 518055 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895164990986","@type":"Researcher","foaf:name":[{"@value":"Bin Cheng"}],"jpcoar:affiliationName":[{"@value":"The State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering Lanzhou University  222 Tianshui South Road Lanzhou 730000 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895164990984","@type":"Researcher","foaf:name":[{"@value":"Yun Li"}],"jpcoar:affiliationName":[{"@value":"The State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering Lanzhou University  222 Tianshui South Road Lanzhou 730000 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895164990980","@type":"Researcher","foaf:name":[{"@value":"Jingjing Guo"}],"jpcoar:affiliationName":[{"@value":"The State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering Lanzhou University  222 Tianshui South Road Lanzhou 730000 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895164990977","@type":"Researcher","foaf:name":[{"@value":"Jing Zhang"}],"jpcoar:affiliationName":[{"@value":"Shenzhen Engineering Laboratory of Nano Drug Slow Release Key Laboratory of Chemical Genomics Shenzhen Graduate School of Peking University  Shenzhen 518055 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895164991104","@type":"Researcher","foaf:name":[{"@value":"Hongbin Zhai"}],"jpcoar:affiliationName":[{"@value":"Shenzhen Engineering Laboratory of Nano Drug Slow Release Key Laboratory of Chemical Genomics Shenzhen Graduate School of Peking University  Shenzhen 518055 China"},{"@value":"The State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering Lanzhou University  222 Tianshui South Road Lanzhou 730000 China"},{"@value":"Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)  Tianjin 300071 China"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00448249"},{"@type":"EISSN","@value":"15213757"}],"prism:publicationName":[{"@value":"Angewandte Chemie"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2017-12-05","prism:volume":"130","prism:number":"4","prism:startingPage":"959","prism:endingPage":"963"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fange.201709762"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201709762"}],"createdAt":"2017-11-08","modifiedAt":"2023-09-14","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050282813382951808","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Concise Construction of the ACDE Ring System of Calyciphylline A Type Alkaloids by a [5+2] Cycloaddition"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/ange.201709762"},{"@type":"CROSSREF","@value":"10.1002/chem.201901690_references_DOI_Q6W6uPpsr5v6MORzYK3M4HOLbgg"}]}