{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362825895185068416.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/zaac.19835061123"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fzaac.19835061123"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/zaac.19835061123"}}],"dc:title":[{"@value":"Vergleichende Untersuchungen an Alkoxy‐trimethylsilanen, Alkoxy‐pentamethyldisilanen und 1,2 Dialkoxy‐tetramethyldisilanen sowie an analogen Alkylamino‐ und Alkylthio‐disilanen"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Zum Vergleich mit bereits früher untersuchten Verbindungen Me<jats:sub>3</jats:sub>SiX (I) und Me<jats:sub>5</jats:sub>Si<jats:sub>2</jats:sub>X (II) mit X  OR, NHR und SR wurden Disilane des Typs XMe<jats:sub>2</jats:sub>SiSiMe<jats:sub>2</jats:sub>X (III) hergestellt. Für alle drei Substanztypen wurden relative Basizitätswerte und NMR‐Daten gemessen sowie für ausgewählte Verbindungen mit X  OR thermodynamische Daten der Assoziation mit Phenol. Die Ergebnisse werden bezüglich der Abhängigkeit von elektronischen und sterischen Effekten diskutiert. Für die Verbindungen mit X  OR und NHR ist der induktive Effekt von X wesentlich stärker durch konjugative Wechselwirkungen kompensiert als für die Verbindungen mit X  SR.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382825895185068417","@type":"Researcher","foaf:name":[{"@value":"R. Stendel"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895185068416","@type":"Researcher","foaf:name":[{"@value":"E. Popowski"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895185068418","@type":"Researcher","foaf:name":[{"@value":"H. Kelling"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00442313"},{"@type":"EISSN","@value":"15213749"}],"prism:publicationName":[{"@value":"Zeitschrift für anorganische und allgemeine Chemie"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"1983-11","prism:volume":"506","prism:number":"11","prism:startingPage":"195","prism:endingPage":"202"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fzaac.19835061123"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/zaac.19835061123"}],"createdAt":"2005-01-02","modifiedAt":"2023-10-08","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Inorganic%20Chemistry","dc:title":"Inorganic Chemistry"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050282813449595136","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Ring-expanding and ring-opening transformations of benzofurans and indoles with introducing heteroatoms"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567179879650432","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Copper‐Catalyzed Ring‐Opening Silylation of Benzofurans with Disilane"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/zaac.19835061123"},{"@type":"CROSSREF","@value":"10.1246/cl.190393_references_DOI_OBJ2wrXKG9NTMER6sBQQxNYbny"},{"@type":"CROSSREF","@value":"10.1002/anie.201806237_references_DOI_OBJ2wrXKG9NTMER6sBQQxNYbny"}]}