{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362825895258434816.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/la050776j"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/la050776j"}},{"identifier":{"@type":"PMID","@value":"16262329"}}],"dc:title":[{"@value":"Electron Transfer in Metal−Molecule−Metal Junction Composed of Self-Assembled Monolayers of Helical Peptides Carrying Redox-Active Ferrocene Units"}],"description":[{"notation":[{"@value":"Electronic properties of three kinds of helical peptides with or without redox-active ferrocene units were investigated by using scanning tunneling microscopy under ultrahigh vacuum. The currents through the helical peptides carrying ferrocene units at the molecular terminals became significantly larger than that through a reference peptide without any ferrocene units. On the other hand, ferrocene units in the middle of the peptide chain did not affect the current-voltage characteristics. These results indicate that the ferrocene units near the metal electrode should play an important role for efficient electron transfer between the metal and the peptide molecules, which process is one of the rate-determining steps for characterizing molecular conductance in metal-molecule-metal junction."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382825895258434818","@type":"Researcher","foaf:name":[{"@value":"Kazuya Kitagawa"}],"jpcoar:affiliationName":[{"@value":"Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-Daigaku-Katsura, Nishikyo-ku, Kyoto 615-8510, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895258434816","@type":"Researcher","foaf:name":[{"@value":"Tomoyuki Morita"}],"jpcoar:affiliationName":[{"@value":"Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-Daigaku-Katsura, Nishikyo-ku, Kyoto 615-8510, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895258434817","@type":"Researcher","foaf:name":[{"@value":"Shunsaku Kimura"}],"jpcoar:affiliationName":[{"@value":"Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-Daigaku-Katsura, Nishikyo-ku, Kyoto 615-8510, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"07437463"},{"@type":"EISSN","@value":"15205827"}],"prism:publicationName":[{"@value":"Langmuir"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2005-09-21","prism:volume":"21","prism:number":"23","prism:startingPage":"10624","prism:endingPage":"10631"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/la050776j"}],"createdAt":"2005-11-01","modifiedAt":"2021-09-21","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Magnetic%20Resonance%20Spectroscopy","dc:title":"Magnetic Resonance Spectroscopy"},{"@id":"https://cir.nii.ac.jp/all?q=Metallocenes","dc:title":"Metallocenes"},{"@id":"https://cir.nii.ac.jp/all?q=Electrons","dc:title":"Electrons"},{"@id":"https://cir.nii.ac.jp/all?q=Ferrous%20Compounds","dc:title":"Ferrous Compounds"},{"@id":"https://cir.nii.ac.jp/all?q=Peptides","dc:title":"Peptides"},{"@id":"https://cir.nii.ac.jp/all?q=Oxidation-Reduction","dc:title":"Oxidation-Reduction"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004233577137280","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Metal array fabrication based on ultrasound-induced self-assembly of metalated dipeptides"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708154722048","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Selective Thermal Elongation of Metal–Metal Distances in the Two-Dimensional Assembly of Ag(I) Ions Templated by Assembled Peptide Ligands"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708585011712","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"ONO-pincer ruthenium complex-bound norvaline for efficient catalytic oxidation of methoxybenzenes with hydrogen peroxide"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183518132608","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Metal array fabrication through self-assembly of Pt-complex-bound amino acids"}]},{"@id":"https://cir.nii.ac.jp/crid/1360869855110395904","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of atom-precise supported metal clusters <i>via</i> solid-phase peptide synthesis"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001206496885760","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"表面科学関連分野での応用：界面計測，表面修飾（STMを用いた自己組織化単分子膜の伝導特性評価）"},{"@value":"電気化学:測定と解析のてびき 表面科学関連分野での応用--界面計測,表面修飾(STMを用いた自己組織化単分子膜の伝導特性評価)"},{"@language":"ja-Kana","@value":"デンキ カガク ソクテイ ト カイセキ ノ テビキ ヒョウメン カガク カンレン ブンヤ デノ オウヨウ カイメン ケイソク ヒョウメン シュウショク STM オ モチイタ ジコ ソシキカ タンブンシマク ノ デンドウ トクセイ ヒョウカ"}]},{"@id":"https://cir.nii.ac.jp/crid/2050588892094607616","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis and structural analysis of ruthenium-bound norvaline peptides"}]},{"@id":"https://cir.nii.ac.jp/crid/2051151842044446720","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis and self-assembling properties of Pt-complex-bound oligo(glutamic 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