{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362825895419058432.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/cssc.201000327"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fcssc.201000327"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/cssc.201000327"}}],"dc:title":[{"@value":"Interconversion between Formic Acid and H<sub>2</sub>/CO<sub>2</sub> using Rhodium and Ruthenium Catalysts for CO<sub>2</sub> Fixation and H<sub>2</sub> Storage"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>The interconversion between formic acid and H<jats:sub>2</jats:sub>/CO<jats:sub>2</jats:sub> using half‐sandwich rhodium and ruthenium catalysts with 4,4’‐dihydroxy‐2,2’‐bipyridine (DHBP) was investigated. The influence of substituents of the bipyridine ligand was studied. Chemical shifts of protons in bipyridine linearly correlated with Hammett substituent constants. In the hydrogenation of CO<jats:sub>2</jats:sub>/bicarbonate to formate under basic conditions, significant activations of the catalysts were caused by the electronic effect of oxyanions generated by deprotonation of the hydroxyl group. Initial turnover frequencies of the ruthenium‐ and rhodium‐DHBP complexes increased 65‐ and 8‐fold, respectively, compared to the corresponding unsubstituted bipyridine complexes. In the decomposition of formic acid under acidic conditions, activity enhancement by the electronic effect of the hydroxyl group was observed for the ruthenium catalyst. The rhodium‐DHBP catalyst showed high activity without CO contamination in a relatively wide pH range. Pressurized H<jats:sub>2</jats:sub> can be obtained using an autoclave reactor. The highest turnover frequency and number were obtained at 80 °C. The catalytic system provides valuable insight into the use of CO<jats:sub>2</jats:sub> as a H<jats:sub>2</jats:sub> storage material by combining CO<jats:sub>2</jats:sub> hydrogenation with formic acid decomposition.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382825895419058434","@type":"Researcher","foaf:name":[{"@value":"Yuichiro Himeda"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895419058432","@type":"Researcher","foaf:name":[{"@value":"Satoru Miyazawa"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825895419058433","@type":"Researcher","foaf:name":[{"@value":"Takuji Hirose"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"18645631"},{"@type":"EISSN","@value":"1864564X"}],"prism:publicationName":[{"@value":"ChemSusChem"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2011-01-26","prism:volume":"4","prism:number":"4","prism:startingPage":"487","prism:endingPage":"493"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fcssc.201000327"},{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/cssc.201000327"}],"createdAt":"2011-01-26","modifiedAt":"2025-10-13","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002216615360384","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A Bifunctional Iridium Catalyst Modified for Persistent Hydrogen Generation from Formic Acid: Understanding Deactivation via Cyclometalation of a 1,2-Diphenylethylenediamine Motif"}]},{"@id":"https://cir.nii.ac.jp/crid/1360017282445401984","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Colloidal platinum nanoparticles dispersed by polyvinylpyrrolidone and poly(diallyldimethylammonium chloride) with high catalytic activity for hydrogen production based on formate decomposition"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691660101760","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691853310208","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Catalytic interconversion between hydrogen and formic acid at ambient temperature and pressure"}]},{"@id":"https://cir.nii.ac.jp/crid/1360294643751569024","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Ru complex and N, P-containing polymers confined within mesoporous hollow carbon spheres for hydrogenation of CO2 to formate"}]},{"@id":"https://cir.nii.ac.jp/crid/1360306905621457792","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Water-Induced Switching in Selectivity and Steric Control of Activity in Photochemical CO\n                    <sub>2</sub>\n                    Reduction Catalyzed by RhCp*(bpy) Derivatives"}]},{"@id":"https://cir.nii.ac.jp/crid/1360306906087550464","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Visible-light responsive hydrogen production from formate with a photoredox system using enzymes and colloidal platinum nanoparticles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183521058432","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Hydrogen storage and evolution catalysed by metal hydride complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183536996992","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Catalytic hydrogen production from paraformaldehyde and water using an organoiridium complex"}]},{"@id":"https://cir.nii.ac.jp/crid/1360568467272128256","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Metal-catalyzed hydrogenation and dehydrogenation reactions for efficient hydrogen storage"}]},{"@id":"https://cir.nii.ac.jp/crid/1360572092467390592","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Catalytic mechanism for selective hydrogen production based on formate decomposition with polyvinylpyrrolidone-dispersed platinum nanoparticles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360572092658778368","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Cooperative Effects of Heterodinuclear Ir<sup>III</sup>–M<sup>II</sup> Complexes on Catalytic H<sub>2</sub> Evolution from Formic Acid Dehydrogenation in Water"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658515608320","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Catalytic oxidation of formic acid by dioxygen with an organoiridium complex"}]},{"@id":"https://cir.nii.ac.jp/crid/1360853567442043136","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Enhancement of catalytic activity for selective hydrogen production from formate with homogeneously poly(vinylpyrrolidone)/cationic poly(<scp>l</scp>-lysine) dispersed platinum nanoparticles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360869855574248448","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Toward Methanol Production by CO<sub>2</sub> Hydrogenation beyond Formic Acid Formation"}]},{"@id":"https://cir.nii.ac.jp/crid/1361694367869155968","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"CO<sub>2</sub> Hydrogenation and Formic Acid Dehydrogenation Using Ir Catalysts with Amide-Based Ligands"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107368357553920","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Cationic poly-<scp>l</scp>-amino acid-enhanced selective hydrogen production based on formate decomposition with platinum nanoparticles dispersed by polyvinylpyrrolidone"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680167832448","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Iridium Catalysts with Diazole-containing Ligands for Hydrogen Generation by Formic Acid Dehydrogenation"},{"@language":"ja","@value":"ギ酸の脱水素反応による水素生成のためのジアゾールを配位子に含むイリジウム触媒"}]},{"@id":"https://cir.nii.ac.jp/crid/1390288547259202176","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Mechanistic Study of Hydrogen Production Based on the Formate Decomposition with Platinum Nanoparticles Dispersed by Polyvinylpyrrolidone"},{"@language":"ja","@value":"ポリビニルピロリドンで分散した白金微粒子を触媒とするギ酸分解に基づく水素生成機構"}]},{"@id":"https://cir.nii.ac.jp/crid/1523669554696903680","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Selected Paper : Development of Highly Active Ir-PNP Catalysts for Hydrogenation of Carbon Dioxide with Organic Bases"}]},{"@id":"https://cir.nii.ac.jp/crid/2051996266980552448","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Selective hydrogen production from formate using nanoparticle with homogeneously polymer-dispersed platinum clusters"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/cssc.201000327"},{"@type":"CROSSREF","@value":"10.1021/acscatal.7b01068_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1627/jpi.64.203_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1039/d2se00865c_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1039/c2ee03315a_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1246/cl.190311_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1007/s12274-021-3792-2_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1021/jacs.4c09486_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1039/d4se01245c_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1039/c2dt31823g_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1039/c4cc06581f_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1016/j.tet.2020.130946_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1039/d0se00363h_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1021/acs.inorgchem.0c00812_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1039/c4cy00957f_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20150311_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1039/d0nj02032j_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1039/d1nj01181b_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1021/acs.accounts.4c00411_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1627/jpi.60.53_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1021/om2010172_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"},{"@type":"CROSSREF","@value":"10.1021/acs.organomet.9b00809_references_DOI_UCLm9vtUAiGaympV834BF4bqdp3"}]}