{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362825896245139840.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/anie.201812865"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201812865"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201812865"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.201812865"}}],"dc:title":[{"@value":"Air‐Stable, Lead‐Free Zero‐Dimensional Mixed Bismuth‐Antimony Perovskite Single Crystals with Ultra‐broadband Emission"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Lead‐free zero‐dimensional (0D) organic‐inorganic metal halide perovskites have recently attracted increasing attention for their excellent photoluminescence properties and chemical stability. Here, we report the synthesis and characterization of an air‐stable 0D mixed metal halide perovskite (C<jats:sub>8</jats:sub>NH<jats:sub>12</jats:sub>)<jats:sub>4</jats:sub>Bi<jats:sub>0.57</jats:sub>Sb<jats:sub>0.43</jats:sub>Br<jats:sub>7</jats:sub>⋅H<jats:sub>2</jats:sub>O, in which individual [BiBr<jats:sub>6</jats:sub>]<jats:sup>3−</jats:sup> and [SbBr<jats:sub>6</jats:sub>]<jats:sup>3−</jats:sup> octahedral units are completely isolated and surrounded by the large organic cation C<jats:sub>8</jats:sub>H<jats:sub>12</jats:sub>N<jats:sup>+</jats:sup>. Upon photoexcitation, the bulk crystals exhibit ultra‐broadband emission ranging from 400 to 850 nm, which originates from both free excitons and self‐trapped excitons. This is the first example of 0D perovskites with broadband emission spanning the entire visible spectrum. In addition, (C<jats:sub>8</jats:sub>NH<jats:sub>12</jats:sub>)<jats:sub>4</jats:sub>Bi<jats:sub>0.57</jats:sub>Sb<jats:sub>0.43</jats:sub>Br<jats:sub>7</jats:sub>⋅H<jats:sub>2</jats:sub>O exhibits excellent humidity and light stability. These findings present a new direction towards the design of environmentally‐friendly, high‐performance 0D perovskite light emitters.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382825896245139840","@type":"Researcher","foaf:name":[{"@value":"Ruiling Zhang"}],"jpcoar:affiliationName":[{"@value":"State Key Laboratory of Molecular Reaction Dynamics Dalian Institute of Chemical Physics Chinese Academy of Science  Dalian 116023 P. R. China"},{"@value":"University of the Chinese Academy of Sciences  Beijing 100039 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825896245139843","@type":"Researcher","foaf:name":[{"@value":"Xin Mao"}],"jpcoar:affiliationName":[{"@value":"State Key Laboratory of Molecular Reaction Dynamics Dalian Institute of Chemical Physics Chinese Academy of Science  Dalian 116023 P. R. China"},{"@value":"University of the Chinese Academy of Sciences  Beijing 100039 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825896245139847","@type":"Researcher","foaf:name":[{"@value":"Yang Yang"}],"jpcoar:affiliationName":[{"@value":"State Key Laboratory of Molecular Reaction Dynamics Dalian Institute of Chemical Physics Chinese Academy of Science  Dalian 116023 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825896245139842","@type":"Researcher","foaf:name":[{"@value":"Songqiu Yang"}],"jpcoar:affiliationName":[{"@value":"State Key Laboratory of Molecular Reaction Dynamics Dalian Institute of Chemical Physics Chinese Academy of Science  Dalian 116023 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825896245139846","@type":"Researcher","foaf:name":[{"@value":"Wenyuan Zhao"}],"jpcoar:affiliationName":[{"@value":"State Key Laboratory of Molecular Reaction Dynamics Dalian Institute of Chemical Physics Chinese Academy of Science  Dalian 116023 P. R. China"},{"@value":"University of the Chinese Academy of Sciences  Beijing 100039 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825896245139844","@type":"Researcher","foaf:name":[{"@value":"Tuerdi Wumaier"}],"jpcoar:affiliationName":[{"@value":"Department of physics Xinjiang Institute of Engineering  Urumqi Xinjiang 830091 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825896245139845","@type":"Researcher","foaf:name":[{"@value":"Donghui Wei"}],"jpcoar:affiliationName":[{"@value":"College of Chemistry and Molecular Engineering, Zhengzhou University  100 Science Avenue Zhengzhou P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825896245139968","@type":"Researcher","foaf:name":[{"@value":"Weiqiao Deng"}],"jpcoar:affiliationName":[{"@value":"State Key Laboratory of Molecular Reaction Dynamics Dalian Institute of Chemical Physics Chinese Academy of Science  Dalian 116023 P. R. China"},{"@value":"Institute of Molecular Sciences and Engineering, Shandong University  Qingdao P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825896245139841","@type":"Researcher","foaf:name":[{"@value":"Keli Han"}],"jpcoar:affiliationName":[{"@value":"State Key Laboratory of Molecular Reaction Dynamics Dalian Institute of Chemical Physics Chinese Academy of Science  Dalian 116023 P. R. China"},{"@value":"Institute of Molecular Sciences and Engineering, Shandong University  Qingdao P. R. China"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14337851"},{"@type":"EISSN","@value":"15213773"}],"prism:publicationName":[{"@value":"Angewandte Chemie International Edition"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2019-02-07","prism:volume":"58","prism:number":"9","prism:startingPage":"2725","prism:endingPage":"2729"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201812865"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201812865"},{"@id":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.201812865"}],"createdAt":"2019-01-21","modifiedAt":"2023-09-08","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360025429427222912","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Evolution of fractal patterns in lead-free zero-dimensional perovskite Cs<sub>2</sub>InBr<sub>5</sub>(H<sub>2</sub>O)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360298757199996672","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Inorganic Chain Mediated Excitonic Properties in One-Dimensional Lead Halide Hybrid Perovskites"}]},{"@id":"https://cir.nii.ac.jp/crid/1360572092436619776","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Bismuth-Based Zero-Dimensional Perovskite-like Materials: Effect of Benzylammonium on Dielectric Confinement and Photoconductivity"}]},{"@id":"https://cir.nii.ac.jp/crid/1360849942950363392","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Remote Tuning of Bandgap and Emission of Lead Perovskites by Spatially Controlled Halide Exchange Reactions"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/anie.201812865"},{"@type":"CROSSREF","@value":"10.1039/d4ce00204k_references_DOI_XZFjYgulOZL0znYSsWZGu0QDP1X"},{"@type":"CROSSREF","@value":"10.1021/acs.jpclett.2c01978_references_DOI_XZFjYgulOZL0znYSsWZGu0QDP1X"},{"@type":"CROSSREF","@value":"10.1021/acs.chemmater.0c00390_references_DOI_XZFjYgulOZL0znYSsWZGu0QDP1X"},{"@type":"CROSSREF","@value":"10.1021/acsmaterialslett.0c00036_references_DOI_XZFjYgulOZL0znYSsWZGu0QDP1X"}]}