{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362825896370162048.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/ejoc.201100313"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.201100313"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/ejoc.201100313"}}],"dc:title":[{"@value":"Site‐Selective Synthesis of Arylated Indenones by Suzuki–Miyaura Cross‐Coupling Reactions of 2,3,5‐Tribromoinden‐1‐one"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>The first transition‐metal‐catalyzed cross‐coupling reactions of 2,3,5‐tribromo‐1<jats:italic>H</jats:italic>‐inden‐1‐one are reported. The Suzuki–Miyaura reaction of 2,3,5‐tribromo‐1<jats:italic>H</jats:italic>‐inden‐1‐one with three equivalents of arylboronic acid gave 2,3,5‐triaryl‐1<jats:italic>H</jats:italic>‐inden‐1‐ones. The reaction with one and two equivalents of arylboronic acid gave 2,5‐dibromo‐3‐aryl‐1<jats:italic>H</jats:italic>‐inden‐1‐ones and 5‐bromo‐2,3‐diaryl‐1<jats:italic>H</jats:italic>‐inden‐1‐ones, respectively, with very good site‐selectivity. The one‐pot reaction of 2,3,5‐tribromo‐1<jats:italic>H</jats:italic>‐inden‐1‐one with one equivalent of two different arylboronic acids afforded 5‐bromo‐2,3‐diaryl‐1<jats:italic>H</jats:italic>‐inden‐1‐ones containing two different terminal aryl groups. Other one‐pot reactions allowed the synthesis of 2,3,5‐triaryl‐1<jats:italic>H</jats:italic>‐inden‐1‐ones containing different aryl groups.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382825896370162048","@type":"Researcher","foaf:name":[{"@value":"Dhafer Saber Zinad"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825896370162050","@type":"Researcher","foaf:name":[{"@value":"Munawar Hussain"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825896370162051","@type":"Researcher","foaf:name":[{"@value":"Alexander Villinger"}]},{"@id":"https://cir.nii.ac.jp/crid/1382825896370162049","@type":"Researcher","foaf:name":[{"@value":"Peter Langer"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"1434193X"},{"@type":"EISSN","@value":"10990690"}],"prism:publicationName":[{"@value":"European Journal of Organic Chemistry"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2011-06","prism:volume":"2011","prism:number":"22","prism:startingPage":"4212","prism:endingPage":"4221"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.201100313"},{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/ejoc.201100313"}],"createdAt":"2011-06-01","modifiedAt":"2025-10-15","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/2050307417127979136","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of indenones through rhodium(Ⅲ)-catalyzed [3+2] annulation utilizing a recyclable carbazolyl leaving group"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/ejoc.201100313"},{"@type":"CROSSREF","@value":"10.1246/cl.200884_references_DOI_6hApdYPh35asjZSQCnr3DmaYBr4"}]}