{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363107369810189312.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1238/physica.topical.115a00943"}},{"identifier":{"@type":"URI","@value":"http://stacks.iop.org/1402-4896/2005/i=T115/a=284/pdf"}},{"identifier":{"@type":"NAID","@value":"30007304545"}}],"dc:title":[{"@value":"Direct Speciation of Lead, Zinc and Antimony in Fly Ash from Waste Treatment Facilities by XAFS spectroscopy"}],"description":[{"notation":[{"@value":"It is important to understand the chemical states of heavy metals in solid waste from municipal incinerator (MSWI) fly ash as both the toxicity and behavior in the environment of heavy metals differ with their chemical states. In this study, direct speciation of lead, antimony and zinc in MSWI fly ash was conducted by XAFS spectroscopy. Three kinds of fly ash from continuous stoker-type MSWIs and a kind of fly ash from an ash melting plant (AMP) were investigated. XAFS measurements were carried out on beam line BL01B1 at SPring-8. The lead, zinc and antimony spectra were collected in fluorescence detection mode at room temperature with a Si (111) or Si (311) monochromator. According to Pb LIII-edge XANES spectra, lead was estimated to be predominantly PbCl2 in MSWI fly ashes and PbO in AMP fly ash. Zinc was estimated to be speciated predominantly as ZnCl2 in MSWI fly ashes and a mixture of 2ZnCO3Zn(OH)2, ZnO and ZnS in AMP fly ash. Antimony K-edge XANES spectra indicated that Sb is five-valent in all the fly ashes."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1582824501036237952","@type":"Researcher","foaf:name":[{"@value":"M. Takaoka"}]},{"@id":"https://cir.nii.ac.jp/crid/1383107369810189315","@type":"Researcher","foaf:name":[{"@value":"T. Yamamoto"}]},{"@id":"https://cir.nii.ac.jp/crid/1383107369810189313","@type":"Researcher","foaf:name":[{"@value":"T. Tanaka"}]},{"@id":"https://cir.nii.ac.jp/crid/1383107369810189317","@type":"Researcher","foaf:name":[{"@value":"K. Oshita"}]},{"@id":"https://cir.nii.ac.jp/crid/1383107369810189314","@type":"Researcher","foaf:name":[{"@value":"T. Uruga"}]},{"@id":"https://cir.nii.ac.jp/crid/1383107369810189312","@type":"Researcher","foaf:name":[{"@value":"N. Takeda"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00318949"},{"@type":"PISSN","@value":"http://id.crossref.org/issn/00318949"}],"prism:publicationName":[{"@value":"Physica Scripta"}],"dc:publisher":[{"@value":"IOP Publishing"}],"prism:publicationDate":"2005","prism:volume":"T115","prism:startingPage":"943"},"reviewed":"false","url":[{"@id":"http://stacks.iop.org/1402-4896/2005/i=T115/a=284/pdf"}],"createdAt":"2005-09-20","modifiedAt":"2020-03-02","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004233186911872","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Coexistence of Cu, Fe, Pb, and Zn Oxides and Chlorides as a Determinant of Chlorinated Aromatics Generation in Municipal Solid Waste Incinerator Fly Ash"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283690891244672","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Interplay of metals and bromine with dioxin-related compounds concentrated in e-waste open burning soil from Agbogbloshie in Accra, Ghana"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708163491072","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Thermochemical Behavior of Lead Adjusting Formation of Chlorinated Aromatics in MSW Fly Ash"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285709423271808","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Characterization of lead, chromium, and cadmium in dust emitted from municipal solid waste incineration plants"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205297142272","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Investigation of Chemical States for Pb of MSWI Residues"},{"@value":"焼却残渣中のPbの化合物形態解析"},{"@language":"ja-Kana","@value":"ショウキャク ザンサ チュウ ノ Pb ノ カゴウブツ ケイタイ カイセキ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679238744192","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy","isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Methods of Determining Lead Speciation in Fly Ash by X-ray Absorption Fine-Structure Spectroscopy and a Sequential Extraction Procedure"}]},{"@id":"https://cir.nii.ac.jp/crid/1390283659870398848","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Crystal Morphology Analysis for Heavy Elements in Municipal Solid Waste Incineration Fly and Bottom Ash by X-ray Characterization Techniques"}]},{"@id":"https://cir.nii.ac.jp/crid/1390565134803740544","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Crystal Morphology Estimation of Trace Elements in MSWI Fly Ash Classified into Different Particle Sizes"},{"@language":"ja","@value":"粒径別都市ごみ焼却飛灰中重金属元素の結晶形態推定"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1238/physica.topical.115a00943"},{"@type":"CIA","@value":"30007304545"},{"@type":"OPENAIRE","@value":"doi_dedup___::b82b9779ed0b0c01d8c8b1e5e7d27032"},{"@type":"CROSSREF","@value":"10.2116/analsci.28.481_references_DOI_J5ISxLJCwWatNL1xjMWdUTUqgGV"},{"@type":"CROSSREF","@value":"10.3985/jjsmcwm.30.144_references_DOI_J5ISxLJCwWatNL1xjMWdUTUqgGV"},{"@type":"CROSSREF","@value":"10.1088/1742-6596/430/1/012095_references_DOI_J5ISxLJCwWatNL1xjMWdUTUqgGV"},{"@type":"CROSSREF","@value":"10.1021/es403585h_references_DOI_J5ISxLJCwWatNL1xjMWdUTUqgGV"},{"@type":"CROSSREF","@value":"10.1021/es303663r_references_DOI_J5ISxLJCwWatNL1xjMWdUTUqgGV"},{"@type":"CROSSREF","@value":"10.1016/j.envpol.2015.11.031_references_DOI_J5ISxLJCwWatNL1xjMWdUTUqgGV"},{"@type":"CROSSREF","@value":"10.2116/analsci.19p374_references_DOI_J5ISxLJCwWatNL1xjMWdUTUqgGV"}]}