{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363388843476388352.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1055/s-0037-1610329"}},{"identifier":{"@type":"URI","@value":"http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0037-1610329.pdf"}}],"dc:title":[{"@value":"Acyl Radical Chemistry via Visible-Light Photoredox Catalysis"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>Visible-light photoredox catalysis enables easy access to acyl radicals under mild reaction conditions. Reactive acyl radicals, generated from various acyl precursors such as aldehydes, α-keto acids, carboxylic acids, anhydrides, acyl thioesters, acyl chlorides, or acyl silanes, can undergo a diverse range of synthetically useful transformations, which were previously difficult or inaccessible. This review summarizes the recent progress on visible-light-driven acyl radical generation using transition-metal photoredox catalysts, metallaphotocatalysts, hypervalent iodine catalysts or organic photocatalysts.</jats:p><jats:p>1 \tIntroduction</jats:p><jats:p>2 \tThe Scope of This Review</jats:p><jats:p>3 \tAldehydes as a Source of Acyl Radicals</jats:p><jats:p>4 \tα-Keto Acids as a Source of Acyl Radicals</jats:p><jats:p>5 \tCarboxylic Acids as a Source of Acyl Radicals</jats:p><jats:p>6 \tAnhydrides as a Source of Acyl Radicals</jats:p><jats:p>7 \tAcyl Thioesters as a Source of Acyl Radicals</jats:p><jats:p>8 \tAcyl Chlorides as a Source of Acyl Radicals</jats:p><jats:p>9 \tAcyl Silanes as a Source of Acyl Radicals</jats:p><jats:p>10 \tConclusions and Future Outlook</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383388843476388354","@type":"Researcher","foaf:name":[{"@value":"Ming-Yu Ngai"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Stony Brook University"},{"@value":"Institute of Chemical Biology and Drug Discovery, Stony Brook University"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388843476388352","@type":"Researcher","foaf:name":[{"@value":"Arghya Banerjee"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Stony Brook University"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388843476388353","@type":"Researcher","foaf:name":[{"@value":"Zhen Lei"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Stony Brook University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00397881"},{"@type":"EISSN","@value":"1437210X"}],"prism:publicationName":[{"@value":"Synthesis"}],"dc:publisher":[{"@value":"Georg Thieme Verlag KG"}],"prism:publicationDate":"2018-12-12","prism:volume":"51","prism:number":"02","prism:startingPage":"303","prism:endingPage":"333"},"reviewed":"false","url":[{"@id":"http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0037-1610329.pdf"}],"createdAt":"2018-12-12","modifiedAt":"2019-01-18","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050577043863015808","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Boronic Acid-Mediated Photocatalysis Enables the Intramolecular Hydroacylation of Olefins Using Carboxylic Acids"},{"@value":"Boronic Acid‐Mediated Photocatalysis Enables the Intramolecular Hydroacylation of Olefins Using Carboxylic Acids"}]},{"@id":"https://cir.nii.ac.jp/crid/1360009142928846976","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Radical Hydroalkylation and Hydroacylation of Alkenes 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