{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363388844148954624.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/chem.201403447"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.201403447"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201403447"}},{"identifier":{"@type":"DOI","@value":"10.1002/chin.201511092"}},{"identifier":{"@type":"PMID","@value":"25077456"}}],"dc:title":[{"@value":"Dual Catalysis with Copper and Rhenium for Trifluoromethylation of Propargylic Alcohols: Efficient Synthesis of α‐Trifluoromethylated Enones"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Trifluoromethylation of propargylic alcohols to provide (<jats:italic>Z</jats:italic>)‐α‐trifluoromethylated enones and β‐unsubstituted α‐trifluoromethylated enones proceeded with high yield and selectivity in the presence of CuI/Re<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>. The <jats:italic>Z</jats:italic> isomer was formed under kinetic control, though it is less stable than the <jats:italic>E</jats:italic> isomer in terms of steric repulsion.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383388844148954625","@type":"Researcher","foaf:name":[{"@value":"Hiromichi Egami"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388844148954626","@type":"Researcher","foaf:name":[{"@value":"Takafumi Ide"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388844148954624","@type":"Researcher","foaf:name":[{"@value":"Masashi Fujita"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388844148954627","@type":"Researcher","foaf:name":[{"@value":"Toshifumi Tojo"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388844148954753","@type":"Researcher","foaf:name":[{"@value":"Yoshitaka Hamashima"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388844148954752","@type":"Researcher","foaf:name":[{"@value":"Mikiko 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