{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363388844408496384.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1063/1.1679903"}},{"identifier":{"@type":"URI","@value":"https://pubs.aip.org/aip/jcp/article-pdf/59/10/5529/18888420/5529_1_online.pdf"}}],"dc:title":[{"@value":"Compressibility of water as a function of temperature and pressure"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>The isothermal compressibility of water from 0 to 100 °C and 0 to 1000 bar has been determined from Wilson's sound velocity measurements which have been normalized to Kell's 1 atm values. The isothermal compressibilities determined from the sound velocities have been fit, with a maximum deviation in compressibility of ± 0.016 × 10−6 bar−1, to an extended bulk modulus equation V 0P/(V0-VP) = B + A1P + A2P2, where V0 and VP are the specific volume at an applied pressure of zero and P; and B, A1, and A2 are temperature dependent constants. Our specific volume results are in reasonable agreement with the work of Kell and Whalley at low pressures; however, our results at high pressures (1000 bar) disagree by as much as 169 ppm (the average deviation is approximately 115 ppm). A comparison of the compressibilities indicates a parabolic shift in Kell and Whalley's work with a maximum of approximately 0.205 × 10−6 bar−1 at 400 bar and 5 °C. Since the velocity of sound data is extremely reliable (± 0.2 m/sec) and the maximum error in the compressibilities derived from the sound data is within ± 0.016 × 10−6 bar−1, our PVT results based upon the sound data are more accurate than any direct measurements made to date.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383388844408496385","@type":"Researcher","foaf:name":[{"@value":"Rana A. Fine"}],"jpcoar:affiliationName":[{"@value":"Rosenstiel School of Marine and Atmospheric Science, University of Miami, Miami, Florida 33149"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388844408496384","@type":"Researcher","foaf:name":[{"@value":"Frank J. Millero"}],"jpcoar:affiliationName":[{"@value":"Rosenstiel School of Marine and Atmospheric Science, University of Miami, Miami, Florida 33149"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00219606"},{"@type":"EISSN","@value":"10897690"}],"prism:publicationName":[{"@value":"The Journal of Chemical Physics"}],"dc:publisher":[{"@value":"AIP Publishing"}],"prism:publicationDate":"1973-11-15","prism:volume":"59","prism:number":"10","prism:startingPage":"5529","prism:endingPage":"5536"},"reviewed":"false","url":[{"@id":"https://pubs.aip.org/aip/jcp/article-pdf/59/10/5529/18888420/5529_1_online.pdf"}],"createdAt":"2004-02-09","modifiedAt":"2024-02-09","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050294186529292416","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Theory of Gas Solubility and Hydrophobic Interaction in Aqueous Electrolyte 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