{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363388844623907328.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/ja073037t"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/ja073037t"}},{"identifier":{"@type":"PMID","@value":"17630744"}}],"dc:title":[{"@value":"Synthesis, Structure of Borylmagnesium, and Its Reaction with Benzaldehyde to Form Benzoylborane"}],"description":[{"notation":[{"@value":"The reaction of boryllithium 2 with 1.0 or 0.5 equiv of MgBr2·OEt2 provided boryl Grignard reagents, borylmagnesium bromides 3 and 4, or bis(boryl)magnesium 5. Structures of 3, 4, and 5 in the crystals and solutions indicated the ionic character of the B−Mg bonds. The reactivity of borylmagnesium 3 with benzaldehyde was different from that of boryllithium 2. Benzoylborane 7 was fully characterized as the first acylborane."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383388844623907329","@type":"Researcher","foaf:name":[{"@value":"Makoto Yamashita"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-0033 Tokyo, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388844623907331","@type":"Researcher","foaf:name":[{"@value":"Yuta Suzuki"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-0033 Tokyo, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388844623907328","@type":"Researcher","foaf:name":[{"@value":"Yasutomo Segawa"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-0033 Tokyo, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388844623907330","@type":"Researcher","foaf:name":[{"@value":"Kyoko Nozaki"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-0033 Tokyo, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00027863"},{"@type":"EISSN","@value":"15205126"}],"prism:publicationName":[{"@value":"Journal of the American Chemical Society"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2007-07-14","prism:volume":"129","prism:number":"31","prism:startingPage":"9570","prism:endingPage":"9571"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/ja073037t"}],"createdAt":"2007-07-14","modifiedAt":"2021-10-10","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Boron%20Compounds","dc:title":"Boron Compounds"},{"@id":"https://cir.nii.ac.jp/all?q=Models,%20Molecular","dc:title":"Models, Molecular"},{"@id":"https://cir.nii.ac.jp/all?q=Molecular%20Structure","dc:title":"Molecular Structure"},{"@id":"https://cir.nii.ac.jp/all?q=Benzaldehydes","dc:title":"Benzaldehydes"},{"@id":"https://cir.nii.ac.jp/all?q=Magnesium","dc:title":"Magnesium"},{"@id":"https://cir.nii.ac.jp/all?q=Boranes","dc:title":"Boranes"},{"@id":"https://cir.nii.ac.jp/all?q=Benzoates","dc:title":"Benzoates"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050579444484880640","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Alkali Chloride Adducts of Acyclic Acylaluminum: Synthesis, Structure, and Reactivity Studies"}]},{"@id":"https://cir.nii.ac.jp/crid/1050587981428623744","@type":"Article","resourceType":"学術雑誌論文(journal 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