{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363388845267604352.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/ja068429z"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/ja068429z"}},{"identifier":{"@type":"PMID","@value":"17279756"}}],"dc:title":[{"@value":"Facile Synthesis of Highly π-Extended Heteroarenes, Dinaphtho[2,3-<i>b</i>:2‘,3‘-<i>f</i>]chalcogenopheno[3,2-<i>b</i>]chalcogenophenes, and Their Application to Field-Effect Transistors"}],"description":[{"notation":[{"@value":"A facile three-step synthetic procedure for highly π-extended heteroarenes, dinaphtho[2,3-b:2‘,3‘-f]thieno[3,2-b]thiophene (DNTT) and dinaphtho[2,3-b:2‘,3‘-f]selenopheno[3,2-b]selenophene (DNSS), was established. Solution UV−vis spectra and electrochemistry indicated that they have relatively low-lying HOMO levels and large HOMO−LUMO energy gaps. OFET devices fabricated with evaporated thin-films of DNTT and DNSS showed excellent FET characteristics in air, and the highest field-effect mobility of DNTT- and DNSS-based OFETs is 2.9 and 1.9 cm2 V-1 s-1, respectively."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383388845267604353","@type":"Researcher","foaf:name":[{"@value":"Tatsuya Yamamoto"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan, and Institute for Advanced Materials Research, Hiroshima University, Higashi-Hiroshima 739-8530, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388845267604352","@type":"Researcher","foaf:name":[{"@value":"Kazuo Takimiya"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan, and Institute for Advanced Materials Research, Hiroshima University, Higashi-Hiroshima 739-8530, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00027863"},{"@type":"EISSN","@value":"15205126"}],"prism:publicationName":[{"@value":"Journal of the American Chemical Society"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2007-02-01","prism:volume":"129","prism:number":"8","prism:startingPage":"2224","prism:endingPage":"2225"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/ja068429z"}],"createdAt":"2007-02-06","modifiedAt":"2021-10-03","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050002213395834752","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Synthesis of the extended phenacene molecules, [10]phenacene and [11]phenacene, and their performance in a field-effect transistor"}]},{"@id":"https://cir.nii.ac.jp/crid/1050013894739566976","@type":"Article","resourceType":"学術雑誌論文(journal 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