{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363388845754020096.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/ange.201411953"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fange.201411953"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201411953"}}],"dc:title":[{"@value":"Direct Trifluoromethylthiolation of Unactivated C(sp<sup>3</sup>)H Using Silver(I) Trifluoromethanethiolate and Potassium Persulfate"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>A practical and efficient method for the direct trifluoromethylthiolation of unactivated C(sp<jats:sup>3</jats:sup>)H bonds by AgSCF<jats:sub>3</jats:sub>/K<jats:sub>2</jats:sub>S<jats:sub>2</jats:sub>O<jats:sub>8</jats:sub> under mild conditions is described. The reaction has a good functional‐group tolerance and good selectivity. Initial mechanistic investigations indicate that the reaction may involve a radical process in which K<jats:sub>2</jats:sub>S<jats:sub>2</jats:sub>O<jats:sub>8</jats:sub> plays key roles in both the activation of the C(sp<jats:sup>3</jats:sup>)H bond and the oxidation of AgSCF<jats:sub>3</jats:sub>.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383388845754020096","@type":"Researcher","foaf:name":[{"@value":"Hao Wu"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388845754020099","@type":"Researcher","foaf:name":[{"@value":"Zhiwei Xiao"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388845754020098","@type":"Researcher","foaf:name":[{"@value":"Junhui Wu"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388845754020225","@type":"Researcher","foaf:name":[{"@value":"Yong Guo"}]},{"@id":"https://cir.nii.ac.jp/crid/1380861295144854016","@type":"Researcher","foaf:name":[{"@value":"Ji‐Chang Xiao"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388845754020097","@type":"Researcher","foaf:name":[{"@value":"Chao Liu"}]},{"@id":"https://cir.nii.ac.jp/crid/1380861295144854017","@type":"Researcher","foaf:name":[{"@value":"Qing‐Yun Chen"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00448249"},{"@type":"EISSN","@value":"15213757"}],"prism:publicationName":[{"@value":"Angewandte Chemie"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2015-02-23","prism:volume":"127","prism:number":"13","prism:startingPage":"4142","prism:endingPage":"4146"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fange.201411953"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201411953"}],"createdAt":"2015-02-23","modifiedAt":"2023-09-14","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1390001204142494208","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of Shelf-Stable Reagents for Fluoro-Functionalization Reactions"},{"@value":"Award Accounts : The Chemical Society of Japan Award for Creative Work for 2014 : Development of Shelf-Stable Reagents for Fluoro-Functionalization Reactions"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/ange.201411953"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20160223_references_DOI_KQVO7mgR9qfIijt2OO7G2QOasLm"}]}