{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363388845960906112.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/anie.201801248"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201801248"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201801248"}}],"dc:title":[{"@value":"Monitoring of the ADP/ATP Ratio by Induced Circularly Polarised Europium Luminescence"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>A series of three europium complexes bearing picolyl amine moieties was found to possess differing binding affinities towards Zn<jats:sup>2+</jats:sup> and three nucleotides: AMP, ADP, and ATP. A large increase in the total emission intensity was observed upon binding Zn<jats:sup>2+</jats:sup>, followed by signal amplification upon the addition of nucleotides. The resulting adducts possessed strong induced circularly polarised emission, with ADP and ATP signals of opposite sign. Model DFT geometries of the adducts suggest the Δ diastereoisomer is preferred for ATP and the Λ isomer for ADP/AMP. This change in sign allows the ADP/ATP (or AMP/ATP) ratio to be assessed by monitoring changes in the emission dissymmetry factor, <jats:italic>g</jats:italic><jats:sub>em</jats:sub>.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383388845960906114","@type":"Researcher","foaf:name":[{"@value":"Sergey Shuvaev"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Durham University  South Road Durham DH1 3LE UK"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388845960906112","@type":"Researcher","foaf:name":[{"@value":"Mark A. Fox"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Durham University  South Road Durham DH1 3LE UK"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388845960906113","@type":"Researcher","foaf:name":[{"@value":"David Parker"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Durham University  South Road Durham DH1 3LE UK"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14337851"},{"@type":"EISSN","@value":"15213773"}],"prism:publicationName":[{"@value":"Angewandte Chemie International Edition"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2018-05-14","prism:volume":"57","prism:number":"25","prism:startingPage":"7488","prism:endingPage":"7492"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201801248"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201801248"}],"createdAt":"2018-03-30","modifiedAt":"2023-09-11","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360306906066189184","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A Binaphthyl Macrocycle Exhibiting Circularly Polarized Luminescence: On–off Switch Triggered by Molecular Recognition"}]},{"@id":"https://cir.nii.ac.jp/crid/1360857593659820416","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A Pyrene‐Modified Serinol Nucleic Acid Nanostructure Converts the Chirality of Threoninol Nucleic Acids into Circularly Polarized Luminescence Signals"}]},{"@id":"https://cir.nii.ac.jp/crid/1360861295471702144","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Highly Fluorescent Bipyrrole‐Based Tetra‐BF<sub>2</sub> Flag‐Hinge Chromophores: Achieving Multicolor and Circularly Polarized Luminescence"}]},{"@id":"https://cir.nii.ac.jp/crid/1361694367883751424","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Steric and Electronic Control of Chiral Eu(III) Complexes for Effective Circularly Polarized Luminescence"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/anie.201801248"},{"@type":"CROSSREF","@value":"10.1002/chem.202500736_references_DOI_EARSq579jFnq9xwDYaKiy4YNd8w"},{"@type":"CROSSREF","@value":"10.1002/chem.202102333_references_DOI_EARSq579jFnq9xwDYaKiy4YNd8w"},{"@type":"CROSSREF","@value":"10.1002/ange.202204358_references_DOI_EARSq579jFnq9xwDYaKiy4YNd8w"},{"@type":"CROSSREF","@value":"10.1021/acsomega.9b03613_references_DOI_EARSq579jFnq9xwDYaKiy4YNd8w"}]}