{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363388846208215936.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1063/1.3569132"}},{"identifier":{"@type":"URI","@value":"https://pubs.aip.org/aip/jcp/article-pdf/doi/10.1063/1.3569132/15438846/124702_1_online.pdf"}}],"dc:title":[{"@value":"Solution-growth kinetics and thermodynamics of nanoporous self-assembled molecular monolayers"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>The temperature and concentration dependences of the self-assembly onto graphite from solution of a series of molecular building blocks able to form nanoporous structures are analyzed experimentally by in situ scanning tunneling microscopy. It is shown that the commonly observed coexistence of dense and nanoporous domains results from kinetic blockades rather than a thermodynamic equilibrium. The ripening can be favored by high densities of domain boundaries, which can be obtained by cooling the substrate before the nucleation and growth. Then ripening at higher-temperature yields large defect-free domains of a single structure. This thermodynamically stable structure can be either the dense or the nanoporous one, depending on the tecton concentration in the supernatant solution. A sharp phase transition from dense to honeycomb structures is observed at a critical concentration. This collective phenomenon is explained by introducing interactions between adsorbed molecules in the thermodynamic description of the whole system.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383388846208215937","@type":"Researcher","foaf:name":[{"@value":"Amandine Bellec"}],"jpcoar:affiliationName":[{"@value":"Service de Physique et Chimie des Surfaces et Interfaces 1 Laboratoire de Nanophotonique, , IRAMIS, CEA, F-91191 Gif-sur-Yvette Cedex, France"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388846208215941","@type":"Researcher","foaf:name":[{"@value":"Claire Arrigoni"}],"jpcoar:affiliationName":[{"@value":"Service de Physique et Chimie des Surfaces et Interfaces 1 Laboratoire de Nanophotonique, , IRAMIS, CEA, F-91191 Gif-sur-Yvette Cedex, France"},{"@value":"Université Pierre et Marie Curie 2 Laboratoire de Chimie des Polymères — UMR7610, , 4 place Jussieu, case 185, F-75252 Paris Cedex 05, France"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388846208215939","@type":"Researcher","foaf:name":[{"@value":"Guillaume Schull"}],"jpcoar:affiliationName":[{"@value":"Service de Physique et Chimie des Surfaces et Interfaces 1 Laboratoire de Nanophotonique, , IRAMIS, CEA, F-91191 Gif-sur-Yvette Cedex, France"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388846208215940","@type":"Researcher","foaf:name":[{"@value":"Ludovic Douillard"}],"jpcoar:affiliationName":[{"@value":"Service de Physique et Chimie des Surfaces et Interfaces 1 Laboratoire de Nanophotonique, , IRAMIS, CEA, F-91191 Gif-sur-Yvette Cedex, France"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388846208215681","@type":"Researcher","foaf:name":[{"@value":"Céline Fiorini-Debuisschert"}],"jpcoar:affiliationName":[{"@value":"Service de Physique et Chimie des Surfaces et Interfaces 1 Laboratoire de Nanophotonique, , IRAMIS, CEA, F-91191 Gif-sur-Yvette Cedex, France"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388846208215936","@type":"Researcher","foaf:name":[{"@value":"Fabrice Mathevet"}],"jpcoar:affiliationName":[{"@value":"Université Pierre et Marie Curie 2 Laboratoire de Chimie des Polymères — UMR7610, , 4 place Jussieu, case 185, F-75252 Paris Cedex 05, France"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388846208215942","@type":"Researcher","foaf:name":[{"@value":"David Kreher"}],"jpcoar:affiliationName":[{"@value":"Université Pierre et Marie Curie 2 Laboratoire de Chimie des Polymères — UMR7610, , 4 place Jussieu, case 185, F-75252 Paris Cedex 05, France"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388846208215938","@type":"Researcher","foaf:name":[{"@value":"André-Jean Attias"}],"jpcoar:affiliationName":[{"@value":"Université Pierre et Marie Curie 2 Laboratoire de Chimie des Polymères — UMR7610, , 4 place Jussieu, case 185, F-75252 Paris Cedex 05, France"}]},{"@id":"https://cir.nii.ac.jp/crid/1383388846208215680","@type":"Researcher","foaf:name":[{"@value":"Fabrice Charra"}],"jpcoar:affiliationName":[{"@value":"Service de Physique et Chimie des Surfaces et Interfaces 1 Laboratoire de Nanophotonique, , IRAMIS, CEA, F-91191 Gif-sur-Yvette Cedex, France"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00219606"},{"@type":"EISSN","@value":"10897690"}],"prism:publicationName":[{"@value":"The Journal of Chemical Physics"}],"dc:publisher":[{"@value":"AIP Publishing"}],"prism:publicationDate":"2011-03-23","prism:volume":"134","prism:number":"12","prism:startingPage":"124702"},"reviewed":"false","url":[{"@id":"https://pubs.aip.org/aip/jcp/article-pdf/doi/10.1063/1.3569132/15438846/124702_1_online.pdf"}],"createdAt":"2011-03-24","modifiedAt":"2023-08-03","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050586411175785856","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Trapping a Pentagonal Molecule in a Self-Assembled Molecular Network: Alkoxylated Isosceles Triangular Molecule Does the Job"},{"@value":"Trapping a pentagonal molecule in a self-assembled molecular network: an alkoxylated isosceles triangular molecule does the job"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002216680340096","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Role of Substrate in Directing the Self-Assembly of Multicomponent Supramolecular Networks at the Liquid–Solid Interface"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233135219584","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"How Does Chemisorption Impact Physisorption? 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