{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670318575902848.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/polb.20823"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fpolb.20823"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/polb.20823"}}],"dc:title":[{"@value":"Aligned single‐wall carbon nanotube polymer composites using an electric field"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>While high shear alignment has been shown to improve the mechanical properties of single‐wall carbon nanotube (SWNT)‐polymer composites, this method does not allow for control over the electrical and dielectric properties of the composite and often results in degradation of these properties. Here, we report a novel method to actively align SWNTs in a polymer matrix, which permits control over the degree of alignment of the SWNTs without the side effects of shear alignment. In this process, SWNTs were aligned via AC field‐induced dipolar interactions among the nanotubes in a liquid matrix followed by immobilization by photopolymerization under continued application of the electric field. Alignment of SWNTs was controlled as a function of magnitude, frequency, and application time of the applied electric field. The degree of SWNT alignment was assessed using optical microscopy and polarized Raman spectroscopy, and the morphology of the aligned nanocomposites was investigated by high‐resolution scanning electron microscopy. The structure of the field induced aligned SWNTs was intrinsically different from that of shear aligned SWNTs. In the present work, SWNTs are not only aligned along the field, but also migrate laterally to form thick, aligned SWNT percolative columns between the electrodes. The actively aligned SWNTs amplify the electrical and dielectric properties of the composite. All of these properties of the aligned nanocomposites exhibited anisotropic characteristics, which were controllable by tuning the applied field parameters. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1751–1762, 2006</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670318575902725","@type":"Researcher","foaf:name":[{"@value":"Cheol Park"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670318575902726","@type":"Researcher","foaf:name":[{"@value":"John Wilkinson"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670318575902723","@type":"Researcher","foaf:name":[{"@value":"Sumanth Banda"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670318575902722","@type":"Researcher","foaf:name":[{"@value":"Zoubeida Ounaies"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670318575902727","@type":"Researcher","foaf:name":[{"@value":"Kristopher E. Wise"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670318575902724","@type":"Researcher","foaf:name":[{"@value":"Godfrey Sauti"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670318575902720","@type":"Researcher","foaf:name":[{"@value":"Peter T. Lillehei"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670318575902721","@type":"Researcher","foaf:name":[{"@value":"Joycelyn S. Harrison"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"08876266"},{"@type":"EISSN","@value":"10990488"}],"prism:publicationName":[{"@value":"Journal of Polymer Science Part B: Polymer Physics"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2006-05-08","prism:volume":"44","prism:number":"12","prism:startingPage":"1751","prism:endingPage":"1762"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fpolb.20823"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/polb.20823"}],"createdAt":"2006-05-09","modifiedAt":"2024-02-04","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360283690820817664","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Investigation on sensitivity of a polymer/carbon nanotube composite strain sensor"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283693953185792","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Multi-scale numerical simulations of thermal expansion properties of CNT-reinforced nanocomposites"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285706202237952","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Growths of mechanical elasticity and electrical conductance of graphene nanoplatelet/poly(lactic acid) composites under strong electric field: correlation with time evolution of higher order structure of graphene nanoplatelets"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285710907725440","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Interplay between structure and property of graphene nanoplatelet networks formed by an electric field in a poly(lactic acid) matrix"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285711324894080","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Macroscopic Ensembles of Aligned Carbon Nanotubes in Bubble Imprints Studied by Polarized Raman Microscopy"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565170643219328","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Piezoresistive Strain Sensors Made from Carbon Nanotubes Based Polymer Nanocomposites"}]},{"@id":"https://cir.nii.ac.jp/crid/1361978698482438912","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Basic Investigation of Epoxy Resin Coatings with Dispersed Carbon Nanotubes"}]},{"@id":"https://cir.nii.ac.jp/crid/1520572359366419328","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Alignment of multiwall carbon nanotubes in polymer composites by dielectrophoresis"},{"@language":"ja-Kana","@value":"Alignment of multiwall carbon nanotubes in polymer composites by dielectrophoresis"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/polb.20823"},{"@type":"CROSSREF","@value":"10.1007/s00397-017-1042-z_references_DOI_8KcCR00YaAbFIr31zetjVM8A9eT"},{"@type":"CROSSREF","@value":"10.1155/2014/632501_references_DOI_8KcCR00YaAbFIr31zetjVM8A9eT"},{"@type":"CROSSREF","@value":"10.3390/s111110691_references_DOI_8KcCR00YaAbFIr31zetjVM8A9eT"},{"@type":"CROSSREF","@value":"10.1186/1556-276x-8-15_references_DOI_8KcCR00YaAbFIr31zetjVM8A9eT"},{"@type":"CROSSREF","@value":"10.1122/1.4975335_references_DOI_8KcCR00YaAbFIr31zetjVM8A9eT"},{"@type":"CROSSREF","@value":"10.1143/jjap.48.035002_references_DOI_8KcCR00YaAbFIr31zetjVM8A9eT"},{"@type":"CROSSREF","@value":"10.1016/j.carbon.2009.10.012_references_DOI_8KcCR00YaAbFIr31zetjVM8A9eT"},{"@type":"CROSSREF","@value":"10.1002/ecj.11555_references_DOI_8KcCR00YaAbFIr31zetjVM8A9eT"}]}