{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670318784454528.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/j.tetlet.2017.10.048"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0040403917313400?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0040403917313400?httpAccept=text/plain"}}],"dc:title":[{"@value":"Recent topics in the desymmetrization of meso-diols"}],"description":[{"notation":[{"@value":"Abstract   The desymmetrization of meso compounds is one of the most effective strategies for asymmetric synthesis. This digest focuses on recent progress in the desymmetrization of meso-diols and their derivatives. The topics discussed here include methods for the enzymatic acylation of meso-diols and the hydrolysis of meso-diesters, acylation, related reactions of meso-diols with organocatalysts and metal catalysts, the oxidation of meso-diols by enzymes, organocatalysts, and metal catalysts, and the desymmetrization of meso-dicarbamates with metal catalysts. The desymmetrization of meso-diols using tandem reactions is also discussed."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670318784454528","@type":"Researcher","foaf:name":[{"@value":"Takeyuki Suzuki"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00404039"}],"prism:publicationName":[{"@value":"Tetrahedron Letters"}],"dc:publisher":[{"@value":"Elsevier BV"}],"prism:publicationDate":"2017-12","prism:volume":"58","prism:number":"51","prism:startingPage":"4731","prism:endingPage":"4739"},"reviewed":"false","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:S0040403917313400?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:S0040403917313400?httpAccept=text/plain"}],"createdAt":"2017-10-19","modifiedAt":"2022-06-25","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050022457825381632","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Enantioselective Synthesis of 2‐Substituted 2‐Hydroxymethylaziridines by Copper‐Catalyzed Sulfonylative Desymmetrization of 2‐Amino‐1,3‐Diols"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004232528076544","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Recent topics in enantioselective acyl transfer reactions with dialkylaminopyridine-based nucleophilic catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360016861561698048","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Chiral Symmetry Breaking of Monoacylated Anhydroerythritols and <i>meso</i>‐1,2‐Diols through Crystallization‐Induced Deracemization"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285711981780864","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Enantioselective Desymmetrization of 1,3-Diols by a Chiral DMAP Derivative"}]},{"@id":"https://cir.nii.ac.jp/crid/1360849942940628608","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Asymmetric Formal Synthesis of (+)-Catharanthine via Desymmetrization of Isoquinuclidine"}]},{"@id":"https://cir.nii.ac.jp/crid/1360853567793161472","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Diastereoselective desymmetric 1,2-cis-glycosylation of meso-diols via chirality transfer from a glycosyl donor"}]},{"@id":"https://cir.nii.ac.jp/crid/1360857593732402944","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Selective Monoacylation of Diols and Asymmetric Desymmetrization of Dialkyl <i>meso</i>-Tartrates Using 2-Pyridyl Esters as Acylating Agents and Metal Carboxylates as Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/2051433317038777600","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Excellent enantioselective organocatalytic one-pot desymmetrization of meso-1,2-diols through asymmetric acylation and silylation by a chiral 1,2-diamine derived from (S)-proline"}]},{"@id":"https://cir.nii.ac.jp/crid/2051714792001900416","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Copper- and borinic acid-catalyzed propargylic etherification of propargylic carbonates"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1016/j.tetlet.2017.10.048"},{"@type":"OPENAIRE","@value":"doi_dedup___::6b5ce482f5cb28eb13a3e22afa9b5130"},{"@type":"CROSSREF","@value":"10.1002/anie.202201268_references_DOI_JiM5XP4SFzW5bEaFXk8MRBYD2LA"},{"@type":"CROSSREF","@value":"10.1021/acs.orglett.9b01198_references_DOI_JiM5XP4SFzW5bEaFXk8MRBYD2LA"},{"@type":"CROSSREF","@value":"10.1246/cl.180123_references_DOI_JiM5XP4SFzW5bEaFXk8MRBYD2LA"},{"@type":"CROSSREF","@value":"10.1246/cl.180697_references_DOI_JiM5XP4SFzW5bEaFXk8MRBYD2LA"},{"@type":"CROSSREF","@value":"10.1016/j.tetlet.2018.03.016_references_DOI_JiM5XP4SFzW5bEaFXk8MRBYD2LA"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20220096_references_DOI_JiM5XP4SFzW5bEaFXk8MRBYD2LA"},{"@type":"CROSSREF","@value":"10.1038/s41467-020-16365-8_references_DOI_JiM5XP4SFzW5bEaFXk8MRBYD2LA"},{"@type":"CROSSREF","@value":"10.1021/acs.joc.9b00827_references_DOI_JiM5XP4SFzW5bEaFXk8MRBYD2LA"},{"@type":"CROSSREF","@value":"10.1002/ajoc.202400643_references_DOI_JiM5XP4SFzW5bEaFXk8MRBYD2LA"}]}