{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670318828857472.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/adsc.200800542"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadsc.200800542"}},{"identifier":{"@type":"URI","@value":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.200800542"}}],"dc:title":[{"@value":"Nickel‐Catalyzed Synthesis of Phosphonium Salts from Aryl Halides and Triphenylphosphine"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>An efficient method to synthesize functionalized tetraarylphosphonium salts is described. The nickel‐catalyzed coupling reaction between aryl iodides, bromides, chlorides, or triflates and triphenylphosphine generates tetraarylphosphonium salts in high yields. The coupling is wide in scope and tolerates a variety of functional groups such as alcohols, amides, ketones, aldehydes, phenols, phosphines and amines.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670318828857472","@type":"Researcher","foaf:name":[{"@value":"David Marcoux"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670318828857473","@type":"Researcher","foaf:name":[{"@value":"André B. Charette"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"16154150"},{"@type":"EISSN","@value":"16154169"}],"prism:publicationName":[{"@value":"Advanced Synthesis & Catalysis"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2008-12","prism:volume":"350","prism:number":"18","prism:startingPage":"2967","prism:endingPage":"2974"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadsc.200800542"},{"@id":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.200800542"}],"createdAt":"2008-12-09","modifiedAt":"2025-10-06","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360005518010511360","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Cyclization of Bisphosphines to Phosphacycles via the Cleavage of Two Carbon–Phosphorus Bonds by Nickel Catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565166568741760","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Tetraarylphosphonium Salt-Catalyzed Carbon Dioxide Fixation at Atmospheric Pressure for the Synthesis of Cyclic Carbonates"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169050553728","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of Phosphaphenalenium Salts via P–C Reductive Elimination at a Ru(II) Center and Their Fluorescence Properties"}]},{"@id":"https://cir.nii.ac.jp/crid/1360579813365029376","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of Tetraarylphosphonium Salts from Triarylphosphines and Aryl Bromides Exploiting Light and Palladium"}]},{"@id":"https://cir.nii.ac.jp/crid/1361694367857883392","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Methoxy Groups Increase Reactivity of Bifunctional Tetraarylphosphonium Salt Catalysts for Carbon Dioxide Fixation: A Mechanistic Study"}]},{"@id":"https://cir.nii.ac.jp/crid/1361694368366439168","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"4-Hydroxymethyl-substituted oxazolidinone synthesis by tetraarylphosphonium salt-catalyzed reactions of glycidols with isocyanates"}]},{"@id":"https://cir.nii.ac.jp/crid/1390295724117106560","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of Phosphonium Ylides as Multifunctional Organocatalysts"},{"@language":"ja","@value":"多機能な分子性触媒を志向したホスホニウムイリドの創製"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/adsc.200800542"},{"@type":"CROSSREF","@value":"10.1021/acscatal.6b02265_references_DOI_D16XZQv23gMxWrXuXIFjoQoEy0W"},{"@type":"CROSSREF","@value":"10.1021/acs.joc.9b02581_references_DOI_D16XZQv23gMxWrXuXIFjoQoEy0W"},{"@type":"CROSSREF","@value":"10.1246/cl.220067_references_DOI_D16XZQv23gMxWrXuXIFjoQoEy0W"},{"@type":"CROSSREF","@value":"10.5059/yukigoseikyokaishi.81.333_references_DOI_D16XZQv23gMxWrXuXIFjoQoEy0W"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20190090_references_DOI_D16XZQv23gMxWrXuXIFjoQoEy0W"},{"@type":"CROSSREF","@value":"10.1039/c9cc01983a_references_DOI_D16XZQv23gMxWrXuXIFjoQoEy0W"},{"@type":"CROSSREF","@value":"10.1021/acs.orglett.9b01355_references_DOI_D16XZQv23gMxWrXuXIFjoQoEy0W"}]}