{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670319057270528.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/recl.19670860506"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Frecl.19670860506"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/recl.19670860506"}}],"dc:title":[{"@value":"Salcomine‐catalyzed oxidations of some phenols: A new method for the preparation of a number of<i>para</i>‐benzoquinones"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Bis(salicylidene)ethylenediiminocobalt(II) (salcomine)* is a homogeneous catalyst for the oxidation of phenols with molecular oxygen in solutions of chloroform or methanol at room temperature. A number of substituted phenols with a free<jats:italic>para</jats:italic>‐position have been studied; in most cases the corresponding<jats:italic>para</jats:italic>‐benzoquinone was the main reaction product. Compounds originating from coupling of aryloxy radicals were also detected or isolated. Some speculations on the mechanism of the reaction have been made.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670319057270528","@type":"Researcher","foaf:name":[{"@value":"H. M. van Dort"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319057270400","@type":"Researcher","foaf:name":[{"@value":"H. J. Geursen"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"01650513"},{"@type":"EISSN","@value":"01650513"}],"prism:publicationName":[{"@value":"Recueil des Travaux Chimiques des Pays-Bas"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"1967-01","prism:volume":"86","prism:number":"5","prism:startingPage":"520","prism:endingPage":"526"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Frecl.19670860506"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/recl.19670860506"}],"createdAt":"2010-09-14","modifiedAt":"2025-02-25","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360013172154750848","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Stereochemical Dichotomy in Two Competing Cascade Processes: Total Syntheses of Both Enantiomers of Spiroxin A"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169056940288","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Physical and Chemical Properties of Mononuclear Cobalt Dioxygen Complexes with Tetraimidazolyl-Substituted Pyridine Chelates"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/recl.19670860506"},{"@type":"CROSSREF","@value":"10.1002/anie.201906762_references_DOI_Z4SxmmaVMrLkwoQWQXxWK3iaYZf"},{"@type":"CROSSREF","@value":"10.1246/bcsj.64.165_references_DOI_Z4SxmmaVMrLkwoQWQXxWK3iaYZf"}]}