{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670319071107200.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/anie.201409990"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201409990"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201409990"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.201409990"}}],"dc:title":[{"@value":"Synthesis and Characterization of 2‐Pyridylsulfur Pentafluorides"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Current approaches to prepare SF<jats:sub>5</jats:sub>‐substituted heterocycles during the synthesis of targeted heterocyclic compounds require the use of SF<jats:sub>5</jats:sub>‐functionalized aryl or alkyne reagents or SF<jats:sub>5</jats:sub>Cl as a source of the SF<jats:sub>5</jats:sub> functional group. Herein we report that excess oxidative fluorination of 2,2′‐dipyridyl disulfide with a KF/Cl<jats:sub>2</jats:sub>/MeCN system leads to the formation of thirteen new 2‐pyridylsulfur chlorotetrafluorides (2‐SF<jats:sub>4</jats:sub>Cl‐pyridines). These molecules are found to undergo further chlorine–fluorine exchange reactions by treatment with silver(I) fluoride enabling ready access to a series of ten new substituted 2‐pyridylsulfur pentafluorides (2‐SF<jats:sub>5</jats:sub>‐pyridines). This is the first preparatively simple and readily scalable example of the transformation of an existing heterocyclic sulfur functionality to prepare SF<jats:sub>5</jats:sub>‐substituted heterocycles.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670319071107201","@type":"Researcher","foaf:name":[{"@value":"Oleksandr S. Kanishchev"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319071107200","@type":"Researcher","foaf:name":[{"@value":"William R. Dolbier"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14337851"},{"@type":"EISSN","@value":"15213773"}],"prism:publicationName":[{"@value":"Angewandte Chemie International Edition"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2014-11-06","prism:volume":"54","prism:number":"1","prism:startingPage":"280","prism:endingPage":"284"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201409990"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201409990"},{"@id":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.201409990"}],"createdAt":"2014-11-06","modifiedAt":"2023-08-29","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004233620710528","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of pyridine <i>trans</i>-tetrafluoro-λ<sup>6</sup>-sulfane derivatives <i>via</i> radical addition"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004234207457280","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"The story of SF<sub>5</sub>-substituted pyridines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360007292698223104","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"AgBF4-Mediated Chlorine-Fluorine Exchange Fluorination for the Synthesis of Pentafluorosulfanyl (Hetero)arenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360298345008878720","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Ethynyl-SF<sub>4</sub>-Pyridines: Reagents for SF<sub>4</sub>-Alkynylation to Carbonyl Compounds"}]},{"@id":"https://cir.nii.ac.jp/crid/1360302865556837376","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Fluoroalkylated hypervalent sulfur fluorides: radical addition of arylchlorotetrafluoro-λ<sup>6</sup>-sulfanes to tetrafluoroethylene"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183591152128","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of aryl and heteroaryl tetrafluoro-λ<sup>6</sup>-sulfanyl chlorides from diaryl disulfides using trichloroisocyanuric acid and potassium fluoride"}]},{"@id":"https://cir.nii.ac.jp/crid/1360572092627384064","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Pyridine tetrafluoro-λ<sup>6</sup>-sulfanyl chlorides: spontaneous addition to alkynes and alkenes in the presence or absence of photo-irradiation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360579813422763520","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of Pyridine-SF4-Alkynes via Light-Promoted Radical Coupling of Pyridine-SF4-Chlorides and EBX Reagents"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848655175407232","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of Phthalocyanines with a Pentafluorosulfanyl Substituent at Peripheral Positions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848657458176000","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Recent advancements in the synthesis of pentafluorosulfanyl (SF5)-containing heteroaromatic compounds"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658071881856","@type":"Article","resourceType":"学術雑誌論文(journal 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