Bis(pentafluorophenyl) disulfide as a hydrogen abstractor and an electron acceptor from the resulting radical intermediate

Masaru Tada, Emi Katayama, Naoto Sakurai, Keita Murofushi

doi:10.1016/j.tetlet.2003.10.211

Bis(pentafluorophenyl) disulfide as a hydrogen abstractor and an electron acceptor from the resulting radical intermediate

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書誌事項

公開日: 2004-01

権利情報

https://www.elsevier.com/tdm/userlicense/1.0/

DOI

10.1016/j.tetlet.2003.10.211

公開者: Elsevier BV

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説明

Abstract The pentafluorobenzenethiyl radical is an efficient hydrogen abstractor from an activated methylene or methine group and bis(pentafluorophenyl) disulfide is an efficient electron acceptor from the resulting radical intermediate. Thus benzyl-OTBS ether was easily converted into the corresponding pinacol, and 2-phenyl-1,3-dioxanes are converted into the monobenzoates of diols.