{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670319592853376.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/ic200786k"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/ic200786k"}},{"identifier":{"@type":"PMID","@value":"21790127"}}],"dc:title":[{"@value":"One-Dimensionally Extended Paddlewheel Dirhodium Complexes from Metal–Metal Bonds with Diplatinum Complexes"}],"description":[{"notation":[{"@value":"We have succeeded in obtaining unique one-dimensional (1D) chain complexes (1, 2, and 3) comprised of two types of metal species: rhodium and platinum. These compounds are constructed from a dinuclear rhodium complex (i.e., [Rh(2)]) and a pivalamidate-bridged platinum complex (i.e., [Pt(2)]), forming an attractive quasi-1D infinite chain, expressed as -{[Rh(2)]-[Pt(2)]-[Pt(2)]}(n)-. Interestingly, the bridging ligands of [Rh(2)] can be varied with trifluoroacetate, acetate, and acetamidate groups, indicating the possibility of electronic structure modulation in the 1D chain."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670319592853376","@type":"Researcher","foaf:name":[{"@value":"Kazuhiro Uemura"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido 1-1, Gifu, 501-1193, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1030003658359735809","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"80201961"},{"@type":"NRID","@value":"1000080201961"},{"@type":"NRID","@value":"9000323296970"},{"@type":"NRID","@value":"9000317561809"},{"@type":"NRID","@value":"9000412687745"},{"@type":"NRID","@value":"9000000260123"},{"@type":"NRID","@value":"9000365510582"},{"@type":"NRID","@value":"9000365515638"},{"@type":"NRID","@value":"9000365515393"},{"@type":"NRID","@value":"9000403595181"},{"@type":"NRID","@value":"9000256013332"},{"@type":"NRID","@value":"9000365515388"},{"@type":"NRID","@value":"9000365515371"},{"@type":"NRID","@value":"9000018493508"},{"@type":"NRID","@value":"9000365510585"},{"@type":"NRID","@value":"9000257719847"},{"@type":"NRID","@value":"9000365510588"},{"@type":"NRID","@value":"9000365515634"},{"@type":"NRID","@value":"9000256011044"},{"@type":"NRID","@value":"9000365515383"},{"@type":"NRID","@value":"9000403595010"},{"@type":"NRID","@value":"9000356514655"},{"@type":"NRID","@value":"9000021805485"},{"@type":"NRID","@value":"9000365515628"},{"@type":"NRID","@value":"9000345446078"},{"@type":"NRID","@value":"9000000796855"},{"@type":"NRID","@value":"9000001847702"},{"@type":"NRID","@value":"9000365515376"},{"@type":"NRID","@value":"9000365515380"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/iridium-ruthenium"}],"foaf:name":[{"@value":"Masahiro Ebihara"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido 1-1, Gifu, 501-1193, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00201669"},{"@type":"EISSN","@value":"1520510X"}],"prism:publicationName":[{"@value":"Inorganic Chemistry"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2011-07-26","prism:volume":"50","prism:number":"17","prism:startingPage":"7919","prism:endingPage":"7921"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/ic200786k"}],"createdAt":"2011-07-26","modifiedAt":"2023-04-22","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002214538262144","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Paddlewheel‐Type Dirhodium Tetrapivalate Based Coordination Polymer: Synthesis, Characterization, and Self‐Assembly and Disassembly 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