{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670319645437696.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1126/science.226.4670.48"}},{"identifier":{"@type":"URI","@value":"https://www.science.org/doi/pdf/10.1126/science.226.4670.48"}}],"dc:title":[{"@value":"X-ray Absorption Spectroscopic Investigation of Sulfur Sites in Coal: Organic Sulfur Identification"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>High-resolution x-ray absorption spectroscopy was used to probe the chemical and structural environments of sulfur in coal. Measurement of the sulfur Kedge spectra down to 2472.0 electron volts under nonvacuum conditions was made possible in an all-helium path, and a Stern-Heald type ion chamber was used for fluorescence detection. For a number of selected sulfur-containing minerals and organic model compounds, results show that near-edge spectral features are diagnostic for sulfur in specific organic moieties such as thiols, disulfides, and various heterocyclics, as well as in mineral sulfide and sulfate phases. The spectrum of a model system containing 35 percent iron pyrite and 65 percent benzothiophene was found to match the observed spectral features of a bituminous coal from the eastern United States.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670319645437698","@type":"Researcher","foaf:name":[{"@value":"C. L. Spiro"}],"jpcoar:affiliationName":[{"@value":"Corporate Research and Development, General Electric Company, Post Office Box 8, Schenectady, New York 12301"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319645437696","@type":"Researcher","foaf:name":[{"@value":"J. Wong"}],"jpcoar:affiliationName":[{"@value":"Corporate Research and Development, General Electric Company, Post Office Box 8, Schenectady, New York 12301"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319645437699","@type":"Researcher","foaf:name":[{"@value":"F. W. Lytle"}],"jpcoar:affiliationName":[{"@value":"Boeing Company, Post Office Box 3999, Seattle, Washington 98124"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319645437697","@type":"Researcher","foaf:name":[{"@value":"R. B. Greegor"}],"jpcoar:affiliationName":[{"@value":"Boeing Company, Post Office Box 3999, Seattle, Washington 98124"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319645437700","@type":"Researcher","foaf:name":[{"@value":"D. H. 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Lamson"}],"jpcoar:affiliationName":[{"@value":"Corporate Research and Development, General Electric Company"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00368075"},{"@type":"EISSN","@value":"10959203"}],"prism:publicationName":[{"@value":"Science"}],"dc:publisher":[{"@value":"American Association for the Advancement of Science (AAAS)"}],"prism:publicationDate":"1984-10-05","prism:volume":"226","prism:number":"4670","prism:startingPage":"48","prism:endingPage":"50"},"reviewed":"false","url":[{"@id":"https://www.science.org/doi/pdf/10.1126/science.226.4670.48"}],"createdAt":"2006-10-05","modifiedAt":"2024-01-12","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360285704780359296","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"An X‐ray spectroscopic perspective on Messinian evaporite from Sicily: Sedimentary fabrics, element distributions, and chemical environments of S and Mg"}]},{"@id":"https://cir.nii.ac.jp/crid/1360849944049027072","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Visualizing sulfur with X-rays: From molecules to tissues"}]},{"@id":"https://cir.nii.ac.jp/crid/1390572433065983360","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of digital oil for technological innovation in petroleum engineering"},{"@language":"ja","@value":"石油工学における技術革新のための デジタルオイルの開発"}]},{"@id":"https://cir.nii.ac.jp/crid/2051433317021985664","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Biomarker records and mineral compositions of the Messinian halite and K–Mg salts from Sicily"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1126/science.226.4670.48"},{"@type":"CROSSREF","@value":"10.1002/2015gc006233_references_DOI_JPSWJew8Zobqaj4BkRetybBDHSA"},{"@type":"CROSSREF","@value":"10.1080/10426507.2019.1602618_references_DOI_JPSWJew8Zobqaj4BkRetybBDHSA"},{"@type":"CROSSREF","@value":"10.1186/s40645-019-0306-x_references_DOI_JPSWJew8Zobqaj4BkRetybBDHSA"},{"@type":"CROSSREF","@value":"10.3720/japt.84.425_references_DOI_JPSWJew8Zobqaj4BkRetybBDHSA"}]}