{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670319795664384.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/chem.200900755"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.200900755"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.200900755"}},{"identifier":{"@type":"PMID","@value":"19714687"}}],"dc:title":[{"@value":"Synthesis, Structures, and Optical and Electrochemical Properties of Benzoporphycenes"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>The first facile syntheses of free‐base di‐ and tetrabenzoporphycenes and their metal complexes are reported, based on retro‐Diels–Alder reactions of the corresponding bicyclo[2.2.2]octadiene‐fused porphycenes, prepared by McMurray coupling of α,α′‐diformyldipyrrole. The photophysical and electrochemical properties are analyzed based on UV/Vis absorption, magnetic circular dichroism (MCD), and fluorescence emission, lifetime and quantum yield measurements, cyclic and differential pulse voltammetry (CV and DPV) and time‐dependent DFT calculations based on B3LYP geometry optimizations. Benzoporphycenes are found to be prime candidates for future use in photodynamic therapy.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670319795664513","@type":"Researcher","foaf:name":[{"@value":"Daiki Kuzuhara"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319795664385","@type":"Researcher","foaf:name":[{"@value":"John Mack"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319795664386","@type":"Researcher","foaf:name":[{"@value":"Hiroko Yamada"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319795664384","@type":"Researcher","foaf:name":[{"@value":"Tetsuo Okujima"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319795664512","@type":"Researcher","foaf:name":[{"@value":"Noboru Ono"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319795664387","@type":"Researcher","foaf:name":[{"@value":"Nagao Kobayashi"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"09476539"},{"@type":"EISSN","@value":"15213765"}],"prism:publicationName":[{"@value":"Chemistry – A European Journal"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2009-09-28","prism:volume":"15","prism:number":"39","prism:startingPage":"10060","prism:endingPage":"10069"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.200900755"},{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.200900755"}],"createdAt":"2009-08-27","modifiedAt":"2025-10-12","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050295834375997568","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Synthesis, structures and properties of benzoporphycenes and naphthoporphycenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1050577309352695808","@type":"Article","resourceType":"学術雑誌論文(journal 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