{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670319807228288.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/j.cplett.2006.06.061"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0009261406009171?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0009261406009171?httpAccept=text/plain"}}],"dc:title":[{"@value":"Photoelectron spectroscopy of acetone cluster anions, <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" altimg=\"si9.gif\" display=\"inline\" overflow=\"scroll\"><mml:mrow><mml:mo stretchy=\"false\">[</mml:mo><mml:mo stretchy=\"false\">(</mml:mo><mml:msub><mml:mrow><mml:mtext>CH</mml:mtext></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mo stretchy=\"false\">)</mml:mo></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub><mml:mtext>CO</mml:mtext><mml:msubsup><mml:mrow><mml:mo stretchy=\"false\">]</mml:mo></mml:mrow><mml:mrow><mml:mi>n</mml:mi></mml:mrow><mml:mrow><mml:mo>-</mml:mo></mml:mrow></mml:msubsup><mml:mspace width=\"0.35em\"/><mml:mo stretchy=\"false\">(</mml:mo><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn>2</mml:mn><mml:mtext>,</mml:mtext><mml:mn>5</mml:mn><mml:ms>–</mml:ms><mml:mn>15</mml:mn><mml:mo stretchy=\"false\">)</mml:mo></mml:mrow></mml:math>"}],"description":[{"notation":[{"@value":"Abstract   Photoelectron images of    [  (    CH    3      )    2    CO    ]    n    -      (  n  =  2  ,  5  –  15  )    were recorded at 3.49 eV. Analysis of the images provided the vertical detachment energies (VDEs) and photoelectron angular distributions (PADs) of    [  (    CH    3      )    2    CO    ]    n    -     . The  n -dependence of these quantities starts with VDE = 0.83 ± 0.03 eV and  β  ≈ −0.3 at  n  = 2, and it ends up with 2.83 ± 0.03 eV and ≈0.1 at  n  = 15. These findings, in conjunction with ab initio results, indicate: (1) the formation of a specific anion structure at  n  = 2; and (2) the presence of a solvent-stabilized (CH 3 ) 2 CO −  valence anion in the larger analogues."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670319807228160","@type":"Researcher","foaf:name":[{"@value":"Ryuzo Nakanishi"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319807228289","@type":"Researcher","foaf:name":[{"@value":"Azusa Muraoka"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319807228288","@type":"Researcher","foaf:name":[{"@value":"Takashi Nagata"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092614"}],"prism:publicationName":[{"@value":"Chemical Physics Letters"}],"dc:publisher":[{"@value":"Elsevier BV"}],"prism:publicationDate":"2006-08","prism:volume":"427","prism:number":"1-3","prism:startingPage":"56","prism:endingPage":"61"},"reviewed":"false","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/","https://www.elsevier.com/legal/tdmrep-license"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:S0009261406009171?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:S0009261406009171?httpAccept=text/plain"}],"createdAt":"2006-06-24","modifiedAt":"2025-09-14","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050303564712194432","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"IR photodissociation spectroscopy of (OCS)n+ and (OCS)n- cluster ions : Similarity and dissimilarity in the structure of CO2, OCS, and CS2 cluster ions"},{"@value":"IR photodissociation spectroscopy of (OCS)<i>n</i>+ and (OCS)<i>n</i>− cluster ions: Similarity and dissimilarity in the structure of CO2, OCS, and CS2 cluster ions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233132102400","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Photoelectron Spectroscopy and Ab Initio Calculations of CS<sub>3</sub><sup>–</sup> Isomers: Carbon Trisulfide and Carbon Disulfide S-Sulfide Anions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658169020928","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Hydrogen-Bond Network Transformation in Water-Cluster Anions Induced by the Complex Formation with Benzene"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1016/j.cplett.2006.06.061"},{"@type":"OPENAIRE","@value":"doi_dedup___::351b1225360d9276098ec578fc340234"},{"@type":"CROSSREF","@value":"10.1021/jz301599f_references_DOI_VesHT4OnjzILfegaDS7e1zBCntr"},{"@type":"CROSSREF","@value":"10.1063/1.4921991_references_DOI_VesHT4OnjzILfegaDS7e1zBCntr"},{"@type":"CROSSREF","@value":"10.1021/acs.jpca.6b06900_references_DOI_VesHT4OnjzILfegaDS7e1zBCntr"}]}