{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670319904120832.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/bm4000822"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/bm4000822"}},{"identifier":{"@type":"PMID","@value":"23391133"}}],"dc:title":[{"@value":"Hydrolytic Activities of Crystalline Cellulose Nanofibers"}],"description":[{"notation":[{"@value":"Cellulose is commonly believed to be inactive to organic substances; this inertness is an essential requirement for raw materials in industrial products. Here we demonstrate the contradictory but promising properties, which are the hydrolytic activities of crystalline cellulose nanofibers for the ester, monophosphate, and even amide bonds of small organic substrates under extremely mild conditions (neutral pH, moderate temperature, and atmospheric pressure). The hydrolytic activities were significantly extended to decompose the coat proteins of model viruses, followed by a drastic decrease in their infection capabilities to the host cells."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670319904120833","@type":"Researcher","foaf:name":[{"@value":"Takeshi Serizawa"}],"jpcoar:affiliationName":[{"@value":"Department\rof Organic and Polymeric\rMaterials, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-H121 Ookayama,\rMeguro-ku, Tokyo 152-8550, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319904120832","@type":"Researcher","foaf:name":[{"@value":"Toshiki Sawada"}],"jpcoar:affiliationName":[{"@value":"Department\rof Organic and Polymeric\rMaterials, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-H121 Ookayama,\rMeguro-ku, Tokyo 152-8550, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319904120835","@type":"Researcher","foaf:name":[{"@value":"Hiromichi Okura"}],"jpcoar:affiliationName":[{"@value":"Department\rof Organic and Polymeric\rMaterials, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-H121 Ookayama,\rMeguro-ku, Tokyo 152-8550, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670319904120834","@type":"Researcher","foaf:name":[{"@value":"Masahisa Wada"}],"jpcoar:affiliationName":[{"@value":"Department of Biomaterials Science,\rGraduate School of Agricultural and Life Science, The University of Tokyo, 1-1-1 Yayoi, Bunkyo-ku, Tokyo 113-8657,\rJapan"},{"@value":"Department of Plant & Environmental New Resources, College of Life Science, Kyung Hee University, 1, Seocheon-dong, Giheung-gu, Yongin-si, Gyeonggi-do 446-701, Republic of Korea"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"15257797"},{"@type":"EISSN","@value":"15264602"}],"prism:publicationName":[{"@value":"Biomacromolecules"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2013-02-13","prism:volume":"14","prism:number":"3","prism:startingPage":"613","prism:endingPage":"617"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/bm4000822"}],"createdAt":"2013-02-07","modifiedAt":"2023-04-16","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Surface%20Properties","dc:title":"Surface Properties"},{"@id":"https://cir.nii.ac.jp/all?q=Hydrolysis","dc:title":"Hydrolysis"},{"@id":"https://cir.nii.ac.jp/all?q=Nanofibers","dc:title":"Nanofibers"},{"@id":"https://cir.nii.ac.jp/all?q=Temperature","dc:title":"Temperature"},{"@id":"https://cir.nii.ac.jp/all?q=Biocompatible%20Materials","dc:title":"Biocompatible Materials"},{"@id":"https://cir.nii.ac.jp/all?q=Hydrogen-Ion%20Concentration","dc:title":"Hydrogen-Ion Concentration"},{"@id":"https://cir.nii.ac.jp/all?q=Particle%20Size","dc:title":"Particle Size"},{"@id":"https://cir.nii.ac.jp/all?q=Cellulose","dc:title":"Cellulose"},{"@id":"https://cir.nii.ac.jp/all?q=Crystallization","dc:title":"Crystallization"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360283694082203008","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Dispersibility of HCl-treated Cellulose Nanocrystals with Water-dispersible Properties in Organic Solvents"}]},{"@id":"https://cir.nii.ac.jp/crid/1360290617490701696","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Self-assembly of cellulose for creating green materials with tailor-made nanostructures"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567180272640000","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Amylose engineering: phosphorylase‐catalyzed polymerization of functional saccharide primers for 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