{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320034186496.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/j.ccr.2006.03.001"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0010854506000701?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0010854506000701?httpAccept=text/plain"}}],"dc:title":[{"@value":"Electronic structures of highly deformed iron(III) porphyrin complexes"}],"description":[{"notation":[{"@value":"Abstract   This review describes the effects of highly deformed porphyrin ring on the electronic structures of iron(III) porphyrinates, which includes (i) the electron configurations in low-spin ( S  = 1/2) ruffled complexes, (ii) the contribution of the intermediate-spin ( S  = 3/2) state in the spin-admixed ( S  = 5/2, 3/2) complexes with ruffled and saddled porphyrin ring, and (iii) the novel spin crossover ( S  = 1/2,  S  = 3/2) phenomenon in saddled complexes, with a special emphasis on the use of  1 H NMR,  13 C NMR, and EPR spectroscopy."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380857691699305088","@type":"Researcher","foaf:name":[{"@value":"Mikio Nakamura"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00108545"}],"prism:publicationName":[{"@value":"Coordination Chemistry Reviews"}],"dc:publisher":[{"@value":"Elsevier BV"}],"prism:publicationDate":"2006-09","prism:volume":"250","prism:number":"17-18","prism:startingPage":"2271","prism:endingPage":"2294"},"reviewed":"false","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/","https://www.elsevier.com/legal/tdmrep-license"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:S0010854506000701?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:S0010854506000701?httpAccept=text/plain"}],"createdAt":"2006-04-18","modifiedAt":"2025-09-14","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002215369669120","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Reductively Induced Catalytic DNA Cleavage of Water Soluble RhIII-Br8TMPyP"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004230099397632","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Different 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