Polyhedral Clathrate Hydrates. X. Structure of the Double Hydrate of Tetrahydrofuran and Hydrogen Sulfide

DOI PDF 被引用文献22件
  • Thomas C. W. Mak
    The Crystallography Laboratory, The University of Pittsburgh, Pittsburgh, Pennsylvania
  • Richard K. McMullan
    The Crystallography Laboratory, The University of Pittsburgh, Pittsburgh, Pennsylvania

書誌事項

公開日
1965-04-15
DOI
  • 10.1063/1.1703229
公開者
AIP Publishing

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説明

<jats:p>The structure of the tetrahydrofuran/hydrogen sulfide double hydrate has been determined from three-dimensional single-crystal data. The analysis confirmed the clathrate host lattice characteristic of 17-Å cubic (Type II) gas hydrates. The hexakaidecahedral voids enclose tetrahydrofuran molecules which appear to undergo free rotation. Statistically, 46% of the pentagonal dodecahedra are occupied by hydrogen sulfide molecules.</jats:p>

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