{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320137012480.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/cssc.201300214"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fcssc.201300214"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/cssc.201300214"}}],"dc:title":[{"@value":"Chemocatalytic Conversion of Ethanol into Butadiene and Other Bulk Chemicals"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>The development of new and improved processes for the synthesis of bio‐based chemicals is one of the scientific challenges of our time. These new discoveries are not only important from an environmental point of view, but also represent an important economic opportunity, provided that the developed processes are selective and efficient. Bioethanol is currently produced from renewable resources in large amounts and, in addition to its use as biofuel, holds considerable promise as a building block for the chemical industry. Indeed, further improvements in production, both in terms of efficiency and feedstock selection, will guarantee availability at competitive prices. The conversion of bioethanol into commodity chemicals, in particular direct ‘drop‐in’ replacements is, therefore, becoming increasingly attractive, provided that the appropriate (catalytic) technology is in place. The production of green and renewable 1,3‐butadiene is a clear example of this approach. The Lebedev process for the one‐step catalytic conversion of ethanol to butadiene has been known since the 1930s and has been applied on an industrial scale to produce synthetic rubber. Later, the availability of low‐cost oil made it more convenient to obtain butadiene from petrochemical sources. The desire to produce bulk chemicals in a sustainable way and the availability of low‐cost bioethanol in large volumes has, however, resulted in a renaissance of this old butadiene production process. This paper reviews the catalytic aspects associated with the synthesis of butadiene via the Lebedev process, as well as the production of other, mechanistically related bulk chemicals that can be obtained from (bio)ethanol.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670320137012481","@type":"Researcher","foaf:name":[{"@value":"Carlo Angelici"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320137012482","@type":"Researcher","foaf:name":[{"@value":"Bert M. Weckhuysen"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320137012480","@type":"Researcher","foaf:name":[{"@value":"Pieter C. A. Bruijnincx"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"18645631"},{"@type":"EISSN","@value":"1864564X"}],"prism:publicationName":[{"@value":"ChemSusChem"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2013-05-23","prism:volume":"6","prism:number":"9","prism:startingPage":"1595","prism:endingPage":"1614"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fcssc.201300214"},{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/cssc.201300214"}],"createdAt":"2013-05-23","modifiedAt":"2025-10-13","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050024953984681216","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Direct ethyl acetate synthesis from ethanol over amorphous-, monoclinic-, tetragonal ZrO2 supported copper 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Ethanol"}]},{"@id":"https://cir.nii.ac.jp/crid/1360298757198872704","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Development of Hf-containing SBA-15 catalysts with highly dispersed active sites for 1,3-butadiene production from ethanol and acetaldehyde"}]},{"@id":"https://cir.nii.ac.jp/crid/1360572184453766912","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Interaction of Ethanol with MgO-SiO<sub>2</sub> Catalysts Studied by TPD Techniques"}]},{"@id":"https://cir.nii.ac.jp/crid/1360576118821474816","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Vapor-phase dehydration of 1,4-butanediol to 1,3-butadiene over Y2Zr2O7 catalyst"}]},{"@id":"https://cir.nii.ac.jp/crid/1360584340697700096","@type":"Article","resourceType":"学術雑誌論文(journal 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Ethanol"},{"@language":"ja","@value":"エタノールからの選択的な1,3-ブタジエン生成におけるMgOの触媒作用とタルク触媒でのZn<sup>2+</sup>の役割"},{"@value":"Catalysis by MgO and the Role of Zn²⁺ in Talc Catalysts for the Selective Production of 1,3-Butadiene from Ethanol"}]},{"@id":"https://cir.nii.ac.jp/crid/1390283659855447936","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"1,3-Butadiene Production by Crotyl Alcohol Dehydration over Solid Acids and Catalyst Deactivation by Water Adsorption"},{"@language":"ja","@value":"クロチルアルコール脱水による1,3-ブタジエン製造と水吸着による触媒活性低下"}]},{"@id":"https://cir.nii.ac.jp/crid/2050588892108642176","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Efficient production of 1,3-butadiene from 1,4-butanediol over Yb2O3 catalyst prepared through hydrothermal 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