{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320285672704.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1063/1.1698631"}},{"identifier":{"@type":"URI","@value":"https://pubs.aip.org/aip/jcp/article-pdf/21/1/87/18802324/87_1_online.pdf"}}],"dc:title":[{"@value":"An Analytical Method of Calculating Variable Diffusion Coefficients"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>The Matano-Boltzmann method of graphical calculation of diffusion coefficients in solutions is replaced by an analytical method in certain systems. This procedure enables accurate calculation of diffusion coefficients near the concentration extremes. An equation is derived for the diffusion coefficient D as a function of concentration c. The equation predicts a variation of D with c which is not exponential in metallic systems, contrary to the proposal of Wagner. Comparison of D values with those obtained graphically, for the system copper-nickel, indicates that the graphical values may be appreciably in error at that extreme where the diffusion coefficient is greatest.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670320285672704","@type":"Researcher","foaf:name":[{"@value":"Lewis D. Hall"}],"jpcoar:affiliationName":[{"@value":"School of Mineral Sciences, Stanford University, Stanford, California"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00219606"},{"@type":"EISSN","@value":"10897690"}],"prism:publicationName":[{"@value":"The Journal of Chemical Physics"}],"dc:publisher":[{"@value":"AIP Publishing"}],"prism:publicationDate":"1953-01-01","prism:volume":"21","prism:number":"1","prism:startingPage":"87","prism:endingPage":"89"},"reviewed":"false","url":[{"@id":"https://pubs.aip.org/aip/jcp/article-pdf/21/1/87/18802324/87_1_online.pdf"}],"createdAt":"2005-01-06","modifiedAt":"2024-02-08","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1390001204246507904","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effect of Pressure on the Anomalous Diffusion of Tin in β-Titanium"},{"@value":"Effect of Pressure on the Anomalous Diffusion of Tin in &beta;-Titanium"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204249042688","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Diffusion of Al and Al-Substituting Elements in Ni<sub>3</sub>Al at Elevated Temperatures"},{"@value":"Diffusion of Al and Al-Substituting Elements in Ni₃Al at Elevated Temperatures"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204249625728","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Interdiffusion in β Phase of the Ternary Ti-Al-V System"},{"@language":"ja","@value":"３元Ｔｉ‐Ａｌ‐Ｖ系のβ相中における相互拡散"},{"@language":"ja-Kana","@value":"Interdiffusion in ベータ phase of the ternary Ti Al V system"},{"@value":"Interdiffusion in &beta; Phase of the Ternary Ti-Al-V System"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205117360512","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Interdiffusion in the α Phase of an Fe–Sb System"},{"@value":"Interdiffusion in the &alpha; Phase of an Fe&ndash;Sb System"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205118798464","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Interdiffusion in Solid Solution of the Al–Ag–Zn System at 832 K"},{"@value":"Interdiffusion in Solid Solution of the Al&ndash;Ag&ndash;Zn System at 832 K"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205119289344","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Interdiffusion in α Solid Solutions of Cu–Al–Zn System"},{"@value":"Interdiffusion in &alpha; Solid Solutions of Cu&ndash;Al&ndash;Zn System"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001206338529920","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Ternary diffusion and thermodynamic interaction in the .BETA. solid solutions of Ti-Al-Co alloys"},{"@language":"ja","@value":"Ｔｉ‐Ａｌ‐Ｃｏ系β固溶体中における三元系拡散と原子間の熱力学的相互作用"},{"@value":"Ti-Al-Co系β固溶体中における三元系拡散と原子間の熱力学的相互作用"},{"@language":"ja-Kana","@value":"Ti Al Coケイ ベータ コヨウタイチュウ ニ オケル 3ゲンケイ カクサン ト ゲンシカン ノ ネツ リキガクテキ ソウゴ サヨウ"},{"@value":"Ternary diffusion and thermodynamic interaction in the β solid solutions of Ti–Al–Co alloys"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001206339488768","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Interdiffusion in the .BETA. solid solution of Ti-Al-Cr system"},{"@language":"ja","@value":"Ｔｉ‐Ａｌ‐Ｃｒ　β固溶体中における相互拡散"}]},{"@id":"https://cir.nii.ac.jp/crid/1390009294965365248","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Ternary diffusion and thermodynamic interaction in the <i>β</i> solid solutions of Ti-Al-Zr alloys at 1473 K"},{"@language":"ja","@value":"Ti-Al-Zr系<i>β</i>固溶体中の1473Kにおける三元系拡散と原子間の熱力学的相互作用"},{"@value":"Ti-Al-Zr系β固溶体中の1473Kにおける三元系拡散と原子間の熱力学的相互作用"},{"@language":"ja-Kana","@value":"Ti-Al-Zrケイvコヨウタイ チュウ ノ 1473K ニ オケル サンゲンケイ カクサン ト ゲンシ カン ノ ネツリキガクテキ ソウゴ サヨウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390017998021531648","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Interdiffusion of Solute Elements in the <i>α</i>-Fe Phase of the Fe–Cr–Mo and Fe–Cr–Si Ternary Systems"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679224933120","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Interdiffusion in Co Solid Solutions of Co-Al-Cr-Ni System at 1423 K"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680094544896","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Ternary Diffusion and Thermodynamic Interactions in α Cu–Ni–Sn Solid Solutions"},{"@value":"Ternary Diffusion and Thermodynamic Interactions in &alpha; Cu&ndash;Ni&ndash;Sn Solid Solutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681315724928","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Interdiffusion in .BETA. phase in the ternary Ti-Al-Fe system alloys"},{"@language":"ja","@value":"Ｔｉ‐Ａｌ‐Ｆｅ三元系合金のβ相中の相互拡散"},{"@value":"Ti-Al-Fe三元系合金のβ相中の相互拡散"},{"@language":"ja-Kana","@value":"Ti Al Fe 3ゲンケイ ゴウキン ノ ベータ ソウチュウ ノ ソウゴ カクサン"},{"@value":"Interdiffusion in β phase in the ternary Ti–Al–Fe system alloys"}]},{"@id":"https://cir.nii.ac.jp/crid/1390294208469050880","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Ternary Diffusion and Thermodynamic Interaction in the β Solid Solutions of Ti–Al–Zr Alloys at 1473 K"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1063/1.1698631"},{"@type":"CROSSREF","@value":"10.2320/matertrans.mra2007110_references_DOI_SGGAGazHf4LiZzv0z21PUjGwJtF"},{"@type":"CROSSREF","@value":"10.2464/jilm.54.280_references_DOI_SGGAGazHf4LiZzv0z21PUjGwJtF"},{"@type":"CROSSREF","@value":"10.2320/jinstmet.72.1044_references_DOI_SGGAGazHf4LiZzv0z21PUjGwJtF"},{"@type":"CROSSREF","@value":"10.2464/jilm.60.444_references_DOI_SGGAGazHf4LiZzv0z21PUjGwJtF"},{"@type":"CROSSREF","@value":"10.2320/matertrans1960.25.142_references_DOI_SGGAGazHf4LiZzv0z21PUjGwJtF"},{"@type":"CROSSREF","@value":"10.2355/isijinternational.isijint-2023-408_references_DOI_SGGAGazHf4LiZzv0z21PUjGwJtF"},{"@type":"CROSSREF","@value":"10.2320/matertrans1960.27.949_references_DOI_SGGAGazHf4LiZzv0z21PUjGwJtF"},{"@type":"CROSSREF","@value":"10.2464/jilm.71.539_references_DOI_SGGAGazHf4LiZzv0z21PUjGwJtF"},{"@type":"CROSSREF","@value":"10.2320/matertrans.mt-l2022018_references_DOI_SGGAGazHf4LiZzv0z21PUjGwJtF"},{"@type":"CROSSREF","@value":"10.2464/jilm.59.432_references_DOI_SGGAGazHf4LiZzv0z21PUjGwJtF"},{"@type":"CROSSREF","@value":"10.2320/matertrans1989.34.763_references_DOI_SGGAGazHf4LiZzv0z21PUjGwJtF"},{"@type":"CROSSREF","@value":"10.2320/matertrans.44.63_references_DOI_SGGAGazHf4LiZzv0z21PUjGwJtF"},{"@type":"CROSSREF","@value":"10.2320/matertrans1960.20.269_references_DOI_SGGAGazHf4LiZzv0z21PUjGwJtF"},{"@type":"CROSSREF","@value":"10.2320/matertrans1960.26.462_references_DOI_SGGAGazHf4LiZzv0z21PUjGwJtF"},{"@type":"CROSSREF","@value":"10.2320/matertrans.m2012218_references_DOI_SGGAGazHf4LiZzv0z21PUjGwJtF"}]}