{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320510018176.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1063/1.1587112"}},{"identifier":{"@type":"URI","@value":"https://pubs.aip.org/aip/jcp/article-pdf/119/5/2538/19322021/2538_1_online.pdf"}}],"dc:title":[{"@value":"Crossed-beam scattering of F+CD4→DF+CD3(νNK): The integral cross sections"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>The title reaction was investigated in a crossed-beam experiment. A (2+1) resonance-enhanced multiphon ionization technique was used to interrogate the internal-state distributions of the CD3 product at three different collision energies. Only the ν2 (umbrella) mode excitation was observed. Its distribution changes from a monotonically declined distribution at low energy to a slightly inverted one at higher collision energy. Although the rotational excitations of CD3 were small, a strong preference for K=0 was found, indicative of the dominance of the tumbling rotation motion of the CD3 product. The vibration-resolved excitation functions were also measured for ν2=0–3. A reaction barrier of 0.5 kcal/mol was deduced.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670320510018179","@type":"Researcher","foaf:name":[{"@value":"Jingang Zhou"}],"jpcoar:affiliationName":[{"@value":"The Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P.O. Box 23-166, Taipei 106, Taiwan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320510018178","@type":"Researcher","foaf:name":[{"@value":"Jim J. Lin"}],"jpcoar:affiliationName":[{"@value":"The Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P.O. Box 23-166, Taipei 106, Taiwan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320510018176","@type":"Researcher","foaf:name":[{"@value":"Weicheng Shiu"}],"jpcoar:affiliationName":[{"@value":"The Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P.O. Box 23-166, Taipei 106, Taiwan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320510018180","@type":"Researcher","foaf:name":[{"@value":"Shih-Chieh Pu"}],"jpcoar:affiliationName":[{"@value":"The Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P.O. Box 23-166, Taipei 106, Taiwan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320510018177","@type":"Researcher","foaf:name":[{"@value":"Kopin Liu"}],"jpcoar:affiliationName":[{"@value":"The Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P.O. Box 23-166, Taipei 106, Taiwan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00219606"},{"@type":"EISSN","@value":"10897690"}],"prism:publicationName":[{"@value":"The Journal of Chemical Physics"}],"dc:publisher":[{"@value":"AIP Publishing"}],"prism:publicationDate":"2003-08-01","prism:volume":"119","prism:number":"5","prism:startingPage":"2538","prism:endingPage":"2544"},"reviewed":"false","url":[{"@id":"https://pubs.aip.org/aip/jcp/article-pdf/119/5/2538/19322021/2538_1_online.pdf"}],"createdAt":"2003-07-17","modifiedAt":"2024-02-07","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360285708534548608","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Rovibrational state specific scattering distributions of the O(1D) + CD4→ OD + CD3 (v1, v2, N) reaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708552432256","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Deuterium isotope effects in the polyatomic reaction of O(1D2) + CH4 → OH + CH3"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1063/1.1587112"},{"@type":"CROSSREF","@value":"10.1039/c0cp01760d_references_DOI_HlOVaGwwI57FeW22G257xLFIbks"},{"@type":"CROSSREF","@value":"10.1039/c3cp51680f_references_DOI_HlOVaGwwI57FeW22G257xLFIbks"}]}