{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320533820544.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/polb.24331"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fpolb.24331"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/polb.24331"}}],"dc:title":[{"@value":"Effect of (3‐glycidyloxypropyl)trimethoxysilane (GOPS) on the electrical properties of PEDOT:PSS films"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>ABSTRACT</jats:title><jats:p>Poly(3,4‐ethylenedioxythiophene) doped with poly(styrenesulfonate) (PEDOT:PSS) has been reported as a successful functional material in a broad variety of applications. One of the most important advantages of PEDOT:PSS is its water‐solubility, which enables simple and environmental friendly manufacturing processes. Unfortunately, this also implies that pristine PEDOT:PSS films are unsuitable for applications in aqueous environments. To reach stability in polar solvents, (3‐glycidyloxypropyl)trimethoxysilane (GOPS) is typically used to cross‐link PEDOT:PSS. Although this strategy is widely used, its mechanism and effect on PEDOT:PSS performance have not been articulated yet. Here, we present a broad study that provides a better understanding of the effect of GOPS on the electrical and electronic properties of PEDOT:PSS. We show that the GOPS reacts with the sulfonic acid group of the excess PSS, causing a change in the PEDOT:PSS film morphology, while the oxidation level of PEDOT remains unaffected. This is at the origin of the observed conductivity changes. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. <jats:bold>2017</jats:bold>, <jats:italic>55</jats:italic>, 814–820</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670320533820676","@type":"Researcher","foaf:name":[{"@value":"Anna Håkansson"}],"jpcoar:affiliationName":[{"@value":"Laboratory of Organic Electronics Department of Science and Technology, Linköping University Norrköping SE‐601 74 Sweden"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320533820546","@type":"Researcher","foaf:name":[{"@value":"Shaobo Han"}],"jpcoar:affiliationName":[{"@value":"Laboratory of Organic Electronics Department of Science and Technology, Linköping University Norrköping SE‐601 74 Sweden"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320533820672","@type":"Researcher","foaf:name":[{"@value":"Suhao Wang"}],"jpcoar:affiliationName":[{"@value":"Laboratory of Organic Electronics Department of Science and Technology, Linköping University Norrköping SE‐601 74 Sweden"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320533820673","@type":"Researcher","foaf:name":[{"@value":"Jun Lu"}],"jpcoar:affiliationName":[{"@value":"Department of Physics Chemistry and Biology, Linköping University Linköping SE‐581 83 Sweden"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320533820674","@type":"Researcher","foaf:name":[{"@value":"Slawomir Braun"}],"jpcoar:affiliationName":[{"@value":"Department of Physics Chemistry and Biology, Linköping University Linköping SE‐581 83 Sweden"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320533820544","@type":"Researcher","foaf:name":[{"@value":"Mats Fahlman"}],"jpcoar:affiliationName":[{"@value":"Department of Physics Chemistry and Biology, Linköping University Linköping SE‐581 83 Sweden"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320533820675","@type":"Researcher","foaf:name":[{"@value":"Magnus Berggren"}],"jpcoar:affiliationName":[{"@value":"Laboratory of Organic Electronics Department of Science and Technology, Linköping University Norrköping SE‐601 74 Sweden"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320533820677","@type":"Researcher","foaf:name":[{"@value":"Xavier Crispin"}],"jpcoar:affiliationName":[{"@value":"Laboratory of Organic Electronics Department of Science and Technology, Linköping University Norrköping SE‐601 74 Sweden"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320533820545","@type":"Researcher","foaf:name":[{"@value":"Simone Fabiano"}],"jpcoar:affiliationName":[{"@value":"Laboratory of Organic Electronics Department of Science and Technology, Linköping University Norrköping SE‐601 74 Sweden"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"08876266"},{"@type":"EISSN","@value":"10990488"}],"prism:publicationName":[{"@value":"Journal of Polymer Science Part B: Polymer Physics"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2017-03-10","prism:volume":"55","prism:number":"10","prism:startingPage":"814","prism:endingPage":"820"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fpolb.24331"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/polb.24331"}],"createdAt":"2017-03-10","modifiedAt":"2023-10-04","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360009142522232320","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"High‐Transconductance Organic Electrochemical Transistor Fabricated on Ultrathin Films Using Spray Coating"}]},{"@id":"https://cir.nii.ac.jp/crid/1360021390761346944","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Dip Coating of Water‐Resistant PEDOT:PSS Films Based on Physical Crosslinking"}]},{"@id":"https://cir.nii.ac.jp/crid/1360294643844387456","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Correlation between Transient Response and Neuromorphic Behavior in Organic Electrochemical Transistors"}]},{"@id":"https://cir.nii.ac.jp/crid/1360306906074353792","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Materials aspects of PEDOT:PSS for neuromorphic organic electrochemical transistors"}]},{"@id":"https://cir.nii.ac.jp/crid/1360572092497502336","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Controlling the Neuromorphic Behavior of Organic Electrochemical Transistors by Blending Mixed and Ion 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