{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320552834176.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1126/science.1082193"}},{"identifier":{"@type":"URI","@value":"https://www.science.org/doi/pdf/10.1126/science.1082193"}}],"dc:title":[{"@value":"On the Origins of Morphological Complexity in Block Copolymer Surfactants"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>\n            Amphiphilic compounds such as lipids and surfactants are fundamental building blocks of soft matter. We describe experiments with poly(\n            <jats:italic>1,2</jats:italic>\n            -butadiene-\n            <jats:italic>b</jats:italic>\n            -ethylene oxide) (PB-PEO) diblock copolymers, which form Y-junctions and three-dimensional networks in water at weight fractions of PEOintermediate to those associated with vesicle and wormlike micelle morphologies. Fragmentation of the network produces a nonergodic array of complex reticulated particles that have been imaged by cryogenic transmission electron microscopy. Data obtained with two sets of PB-PEOcompounds indicate that this type of self-assembly appears above a critical molecular weight. These block copolymers represent versatile amphiphiles, mimicking certain low molecular weight three-component (surfactant/water/oil) microemulsions, without addition of a separate hydrophobe.\n          </jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670320552834177","@type":"Researcher","foaf:name":[{"@value":"Sumeet Jain"}],"jpcoar:affiliationName":[{"@value":"Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455, USA."}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320552834176","@type":"Researcher","foaf:name":[{"@value":"Frank S. Bates"}],"jpcoar:affiliationName":[{"@value":"Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455, USA."}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00368075"},{"@type":"EISSN","@value":"10959203"}],"prism:publicationName":[{"@value":"Science"}],"dc:publisher":[{"@value":"American Association for the Advancement of Science (AAAS)"}],"prism:publicationDate":"2003-04-18","prism:volume":"300","prism:number":"5618","prism:startingPage":"460","prism:endingPage":"464"},"reviewed":"false","url":[{"@id":"https://www.science.org/doi/pdf/10.1126/science.1082193"}],"createdAt":"2003-04-17","modifiedAt":"2024-01-10","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050582252657905920","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Block copolymer self-assembly in ionic 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