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The tert-butyl (or 4-tert-butylphenyl) group can actually function as an end-cap of DB24C8-based rotaxanes when the intercomponent interaction is effectively operative. When such attractive interaction is removed, deslippage occurs. [structure: see text]"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670320575668610","@type":"Researcher","foaf:name":[{"@value":"Yuya Tachibana"}],"jpcoar:affiliationName":[{"@value":"Department of Organic and Polymeric Materials, Tokyo Institute of Technology, Ookayama, Meguro, Tokyo 152-8552, Japan, and Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka 599-8531, 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