{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320649884800.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/fuce.200400020"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Ffuce.200400020"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/fuce.200400020"}}],"dc:title":[{"@value":"PBI‐Based Polymer Membranes for High Temperature Fuel Cells – Preparation, Characterization and Fuel Cell Demonstration"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Proton exchange membrane fuel cell (PEMFC) technology based on perfluorosulfonic acid (PFSA) polymer membranes is briefly reviewed. The newest development in alternative polymer electrolytes for operation above 100 °C is summarized and discussed. As one of the successful approaches to high operational temperatures, the development and evaluation of acid doped polybenzimidazole (PBI) membranes are reviewed, covering polymer synthesis, membrane casting, acid doping, physicochemical characterization and fuel cell testing. A high temperature PEMFC system, operational at up to 200 °C based on phosphoric acid‐doped PBI membranes, is demonstrated. It requires little or no gas humidification and has a CO tolerance of up to several percent. The direct use of reformed hydrogen from a simple methanol reformer, without the need for any further CO removal, has been demonstrated. A lifetime of continuous operation, for over 5000 h at 150 °C, and shutdown‐restart thermal cycle testing for 47 cycles has been achieved. Other issues such as cooling, heat recovery, possible integration with fuel processing units, associated problems and further development are discussed.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670320649884802","@type":"Researcher","foaf:name":[{"@value":"Q. Li"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320649884801","@type":"Researcher","foaf:name":[{"@value":"R. He"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320649884803","@type":"Researcher","foaf:name":[{"@value":"J.O. Jensen"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320649884800","@type":"Researcher","foaf:name":[{"@value":"N.J. Bjerrum"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"16156846"},{"@type":"EISSN","@value":"16156854"}],"prism:publicationName":[{"@value":"Fuel Cells"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2004-07-29","prism:volume":"4","prism:number":"3","prism:startingPage":"147","prism:endingPage":"159"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Ffuce.200400020"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/fuce.200400020"}],"createdAt":"2004-07-29","modifiedAt":"2023-11-16","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360021389822993792","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Ternary Triazole-Based Organic–Inorganic Proton-Conducting Hybrids Based on Computational Models for HT-PEMFC Application"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285707173519104","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Evaluation for sintering of electrocatalysts and its effect on voltage drops in high-temperature proton exchange membrane fuel cells (HT-PEMFC)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285707295778688","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Thin pore-filling membrane with highly packed-acid structure for high temperature and low humidity operating polymer electrolyte fuel cells"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708111725312","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Electronic Structure of a Polybenzimidazole-Wrapped Single-Wall Carbon Nanotube"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658649156480","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Effects of cesium-substituted silicotungstic acid doped with polybenzimidazole membrane for the application of medium temperature polymer electrolyte fuel cells"}]},{"@id":"https://cir.nii.ac.jp/crid/1361412891998304640","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Enhancement of interfacial property by novel solid ionomer CsHSO4-H4SiW12O40 for the three-phase interface of a medium-temperature anhydrous fuel cell"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681474312704","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Soluble Carbon Nanotubes and Application to Electrochemistry"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282763050795136","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Cell performance enhancement with titania-doped polybenzimidazole based composite membrane in intermediate temperature fuel cell under anhydrous condition"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/fuce.200400020"},{"@type":"CROSSREF","@value":"10.1021/acs.jpcc.8b00247_references_DOI_DXJmEKediWUGzNNKdXegayjCvkX"},{"@type":"CROSSREF","@value":"10.1021/acsomega.3c06587_references_DOI_DXJmEKediWUGzNNKdXegayjCvkX"},{"@type":"CROSSREF","@value":"10.2109/jcersj2.18084_references_DOI_DXJmEKediWUGzNNKdXegayjCvkX"},{"@type":"CROSSREF","@value":"10.1016/j.ijhydene.2012.09.016_references_DOI_DXJmEKediWUGzNNKdXegayjCvkX"},{"@type":"CROSSREF","@value":"10.1016/j.jpowsour.2018.05.013_references_DOI_DXJmEKediWUGzNNKdXegayjCvkX"},{"@type":"CROSSREF","@value":"10.5796/electrochemistry.78.2_references_DOI_DXJmEKediWUGzNNKdXegayjCvkX"},{"@type":"CROSSREF","@value":"10.1051/e3sconf/20198301008_references_DOI_DXJmEKediWUGzNNKdXegayjCvkX"},{"@type":"CROSSREF","@value":"10.1016/j.matlet.2019.06.061_references_DOI_DXJmEKediWUGzNNKdXegayjCvkX"}]}