{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320688959104.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1063/1.438331"}},{"identifier":{"@type":"URI","@value":"https://pubs.aip.org/aip/jcp/article-pdf/71/12/5238/18920347/5238_1_online.pdf"}}],"dc:title":[{"@value":"Precise determination of differential electron scattering cross sections. II. CH4, CO2, CF4"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>Precise total (elastic plus inelastic) differential cross sections have been measured for CH4, CO2, and CF4 with 50.4 keV incident electrons. The accuracies are 0.1% in the intensities and ±2 arc sec in the scattering angles. The structure parameters have been evaluated. The bond distances agree well with previous results, although the mean amplitudes of vibration are in general larger than those calculated from harmonic force fields. The difference curves comparing the experimental cross sections to IAM (independent atom model) predictions are discussed utilizing CI atomic potentials in the IAM. The ’’binding’’ energies have been determined and are found to be consistently several electron volts above those evaluated via the heat of combustion.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380848661072067072","@type":"Researcher","foaf:name":[{"@value":"M. Fink"}],"jpcoar:affiliationName":[{"@value":"Physics Department and Electronics Research Center, The University of Texas, Austin, Texas 78712"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320688959104","@type":"Researcher","foaf:name":[{"@value":"C. W. Schmiedekamp"}],"jpcoar:affiliationName":[{"@value":"Physics Department and Electronics Research Center, The University of Texas, Austin, Texas 78712"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320688959105","@type":"Researcher","foaf:name":[{"@value":"D. Gregory"}],"jpcoar:affiliationName":[{"@value":"Physics Department and Electronics Research Center, The University of Texas, Austin, Texas 78712"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00219606"},{"@type":"EISSN","@value":"10897690"}],"prism:publicationName":[{"@value":"The Journal of Chemical Physics"}],"dc:publisher":[{"@value":"AIP Publishing"}],"prism:publicationDate":"1979-12-15","prism:volume":"71","prism:number":"12","prism:startingPage":"5238","prism:endingPage":"5242"},"reviewed":"false","url":[{"@id":"https://pubs.aip.org/aip/jcp/article-pdf/71/12/5238/18920347/5238_1_online.pdf"}],"createdAt":"2003-02-27","modifiedAt":"2024-02-09","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002217836173056","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Interference Effects on (<mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:mi>e</mml:mi></mml:math>,<mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:mn>2</mml:mn><mml:mi>e</mml:mi></mml:math>) Electron Momentum Profiles of<mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:msub><mml:mi>CF</mml:mi><mml:mn>4</mml:mn></mml:msub></mml:math>"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846642021209216","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Experimental and theoretical study on generalized oscillator strengths of the valence-shell electronic excitations in CF4"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644031700864","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Molecular Structure of Bromotrichloromethane as Determined by Gas Electron Diffraction"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848661072067072","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Interference effects on (e, 2e) electron momentum profiles: a\ncomparative study for CCl4 and CF4*"}]},{"@id":"https://cir.nii.ac.jp/crid/1390586963950794112","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"直線分子の計算分子分光学: パラダイムシフトへの挑戦"},{"@language":"en","@value":"Computational Molecular Spectroscopy of Linear Molecules:Challenge for a            Paradigm Shift"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1063/1.438331"},{"@type":"CROSSREF","@value":"10.1103/physrevlett.108.173201_references_DOI_Sh5Yqli759L8EZAvoTUrvHP2I9"},{"@type":"CROSSREF","@value":"10.1246/bcsj.54.2435_references_DOI_Sh5Yqli759L8EZAvoTUrvHP2I9"},{"@type":"CROSSREF","@value":"10.1063/1.3549135_references_DOI_Sh5Yqli759L8EZAvoTUrvHP2I9"},{"@type":"CROSSREF","@value":"10.1140/epjd/e2016-70516-7_references_DOI_Sh5Yqli759L8EZAvoTUrvHP2I9"},{"@type":"CROSSREF","@value":"10.2477/jccj.2021-0049_references_DOI_Sh5Yqli759L8EZAvoTUrvHP2I9"}]}