{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320699342336.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1038/21861"}},{"identifier":{"@type":"URI","@value":"http://www.nature.com/articles/21861.pdf"}},{"identifier":{"@type":"URI","@value":"http://www.nature.com/articles/21861"}}],"dc:title":[{"@value":"Spontaneous assembly of ten components into two interlocked, identical coordination cages"}],"description":[{"notation":[{"@value":"Supermolecules consisting of interlinked ring-like molecules (catenanes)1 are an interesting target for chemical synthesis both for their intrinsic interest as non-covalently bound but robust assemblies and because of the perspective they offer on materials chemistry2. Catenanes have been prepared by metal-ion templating3,4 and self-assembly through other non-covalent interactions5,6,7,8,9,10,11,12. Here we report the synthesis of a catenane composed not of two interlocking rings but of two cages. This structure is prepared by metal-mediated self-assembly13,14,15. The framework of each cage is assembled from five components: two tridentate ligands held together with three metal ions. Because each cage framework can bind an aromatic ring, two cage units will bind one another during their assembly process through the formation of a quadruple aromatic stack, giving rise to the ten-component interlocked supermolecule16,17."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670320699342336","@type":"Researcher","foaf:name":[{"@value":"Makoto Fujita"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320699342337","@type":"Researcher","foaf:name":[{"@value":"Norifumi Fujita"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320699342339","@type":"Researcher","foaf:name":[{"@value":"Katsuyuki Ogura"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320699342338","@type":"Researcher","foaf:name":[{"@value":"Kentaro Yamaguchi"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00280836"},{"@type":"EISSN","@value":"14764687"}],"prism:publicationName":[{"@value":"Nature"}],"dc:publisher":[{"@value":"Springer Science and Business Media LLC"}],"prism:publicationDate":"1999-07","prism:volume":"400","prism:number":"6739","prism:startingPage":"52","prism:endingPage":"55"},"reviewed":"false","dc:rights":["http://www.springer.com/tdm"],"url":[{"@id":"http://www.nature.com/articles/21861.pdf"},{"@id":"http://www.nature.com/articles/21861"}],"createdAt":"2002-07-26","modifiedAt":"2021-12-01","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360285704899701504","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Peptide [4]Catenane by Folding and Assembly"}]},{"@id":"https://cir.nii.ac.jp/crid/1360298336561087616","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Water-driven solid self-assembled catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1360298345008345472","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Self-assembly of nanostructures with high complexity based on metal⋯unsaturated-bond coordination"}]},{"@id":"https://cir.nii.ac.jp/crid/1360298754817820928","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A Face‐to‐Face Dimer of Au<sub>3</sub> Superatoms Supported by Interlocked Tridentate Scaffolds Formed in Au<sub>18</sub>S<sub>2</sub>(SR)<sub>12</sub>"}]},{"@id":"https://cir.nii.ac.jp/crid/1360302474810382720","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Controlling the Assembly of Pd<sup>II</sup>/Bianthryl‐Based Monomeric and Dimeric Interlocked Cages by Steric Effects"}]},{"@id":"https://cir.nii.ac.jp/crid/1360306905616142592","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Step‐by‐Step Self‐Assembly of a Double‐Walled Knotted Cage With Increasing Topological Complexity"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169064369792","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Topologically Different Two Pseudo-decahedral Hydrogen-bond Networks Composed of Triphenylmethylammonium Phosphonates"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567179832705024","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Selective CO<sub>2</sub> Capture and High Proton Conductivity of a Functional Star‐of‐David Catenane Metal–Organic Framework"}]},{"@id":"https://cir.nii.ac.jp/crid/1360580229805413888","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Speed Tuning of the Formation/Dissociation of a Metallorotaxane"}]},{"@id":"https://cir.nii.ac.jp/crid/1360588380127779712","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Topological architectures enriched by cooperative acetylene coordination"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644026925952","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Cyclic and Linear Structures Constructed by Ionic Bonds between Alkali Ion and Pinwheel Pentanuclear [GdIII(CuIIL)4] Core of M[GdIII(CuIIL)4] (M+ = Na+, K+, and Cs+; H3L = <i>N</i>-(4-Methyl-6-oxo-3-azahept-4-enyl)oxamic Acid)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658549728512","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Site-selective anion recognition of an interlocked dimer"}]},{"@id":"https://cir.nii.ac.jp/crid/1361131414402763136","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Self‐Assembly of Coordination Polyhedra with Highly Entangled Faces Induced by Metal–Acetylene Interactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1361131418425559680","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Preparation of cage-shaped hexakis(spiroborate)s"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205298155264","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"配位結合を活用した自己組織化の化学"},{"@language":"en","@value":"Molecular Self-Assembly Based on Coordination Chemistry"},{"@value":"Award Accounts 配位結合を活用した自己組織化の化学"},{"@language":"ja-Kana","@value":"Award Accounts ハイイ ケツゴウ オ カツヨウ シタ ジコ ソシキカ ノ カガク"}]},{"@id":"https://cir.nii.ac.jp/crid/2050588892093641344","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Self-assembled cages and capsules using cyclotriveratrylene-type scaffolds"}]},{"@id":"https://cir.nii.ac.jp/crid/2050588892102334592","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Metal-organic cages (MOCs) : from discrete to cage-based extended architectures"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1038/21861"},{"@type":"OPENAIRE","@value":"doi_dedup___::61f0fcaed54bc268ed137770fc8562c2"},{"@type":"CROSSREF","@value":"10.4019/bjscc.57.13_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1002/anie.201600480_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1246/cl.190731_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1016/j.jorganchem.2022.122318_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1002/anie.202113275_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1016/j.ccr.2022.214605_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1002/chem.202500009_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1002/adma.201703301_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1246/cl.2007.1390_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1002/anie.202217048_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1002/ceur.202300047_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1007/s10847-025-01297-x_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1039/c7ob00328e_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1002/anie.201913142_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1039/d0ob00518e_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20100223_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"},{"@type":"CROSSREF","@value":"10.1246/cl.160780_references_DOI_NcfjnK8DDEjuX6tl6ekV6wDcnDN"}]}