{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320727649792.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1126/science.1083176"}},{"identifier":{"@type":"URI","@value":"https://www.science.org/doi/pdf/10.1126/science.1083176"}},{"identifier":{"@type":"DOI","@value":"10.1002/chin.200334036"}},{"identifier":{"@type":"PMID","@value":"12738860"}}],"dc:title":[{"@value":"Efficient Epoxidation of Olefins with ≥99% Selectivity and Use of Hydrogen Peroxide"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>\n                    Epoxides are an important class of industrial chemicals that have been used as chemical intermediates. Catalytic epoxidation of olefins affords an interesting production technology. We found a widely usable green route to the production of epoxides: A silicotungstate compound, [γ-SiW\n                    <jats:sub>10</jats:sub>\n                    O\n                    <jats:sub>34</jats:sub>\n                    (H\n                    <jats:sub>2</jats:sub>\n                    O)\n                    <jats:sub>2</jats:sub>\n                    ]\n                    <jats:sup>4–</jats:sup>\n                    , is synthesized by protonation of a divacant, lacunary, Keggin-type polyoxometalate of [γ-SiW\n                    <jats:sub>10</jats:sub>\n                    O\n                    <jats:sub>36</jats:sub>\n                    ]\n                    <jats:sup>8–</jats:sup>\n                    and exhibits high catalytic performance for the epoxidation of various olefins, including propylene, with a hydrogen peroxide (H\n                    <jats:sub>2</jats:sub>\n                    O\n                    <jats:sub>2</jats:sub>\n                    ) oxidant at 305 kelvin. The effectiveness of this catalyst is evidenced by ≥99% selectivity to epoxide, ≥99% efficiency of H\n                    <jats:sub>2</jats:sub>\n                    O\n                    <jats:sub>2</jats:sub>\n                    utilization, high stereospecificity, and easy recovery of the catalyst from the homogeneous reaction mixture.\n                  </jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670320727649792","@type":"Researcher","foaf:name":[{"@value":"Keigo Kamata"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, School of Engineering, University of Tokyo, 7-3-1 Hongo, Bunkyoku, Tokyo 113-8656, Japan."},{"@value":"Strategic Technology Research, Nippon Shokubai, 5-8 Nishi Otabi-cho, Suita, Osaka 564-8512, Japan."}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320727649795","@type":"Researcher","foaf:name":[{"@value":"Koji Yonehara"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, School of Engineering, University of Tokyo, 7-3-1 Hongo, Bunkyoku, Tokyo 113-8656, Japan."},{"@value":"Strategic Technology Research, Nippon Shokubai, 5-8 Nishi Otabi-cho, Suita, Osaka 564-8512, Japan."}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320727649793","@type":"Researcher","foaf:name":[{"@value":"Yasutaka Sumida"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, School of Engineering, University of Tokyo, 7-3-1 Hongo, Bunkyoku, Tokyo 113-8656, Japan."},{"@value":"Strategic Technology Research, Nippon Shokubai, 5-8 Nishi Otabi-cho, Suita, Osaka 564-8512, Japan."}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320727649796","@type":"Researcher","foaf:name":[{"@value":"Kazuya Yamaguchi"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, School of Engineering, University of Tokyo, 7-3-1 Hongo, Bunkyoku, Tokyo 113-8656, Japan."},{"@value":"Strategic Technology Research, Nippon Shokubai, 5-8 Nishi Otabi-cho, Suita, Osaka 564-8512, Japan."}]},{"@id":"https://cir.nii.ac.jp/crid/1420564276170374400","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"10282857"},{"@type":"NRID","@value":"1000010282857"},{"@type":"NRID","@value":"9000018153087"},{"@type":"NRID","@value":"9000000966597"},{"@type":"NRID","@value":"9000001308051"},{"@type":"NRID","@value":"9000001222502"},{"@type":"NRID","@value":"9000265565404"},{"@type":"NRID","@value":"9000272989573"},{"@type":"NRID","@value":"9000007287112"},{"@type":"NRID","@value":"9000412337622"},{"@type":"NRID","@value":"9000257720784"},{"@type":"NRID","@value":"9000006562124"},{"@type":"NRID","@value":"9000256022062"},{"@type":"NRID","@value":"9000001115864"},{"@type":"NRID","@value":"9000018809532"},{"@type":"NRID","@value":"9000255700672"},{"@type":"NRID","@value":"9000257717606"},{"@type":"NRID","@value":"9000257715754"},{"@type":"NRID","@value":"9000241781592"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/hikichi_23-822_3890"}],"foaf:name":[{"@value":"Shiro Hikichi"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, School of Engineering, University of Tokyo, 7-3-1 Hongo, Bunkyoku, Tokyo 113-8656, Japan."},{"@value":"Strategic Technology Research, Nippon Shokubai, 5-8 Nishi Otabi-cho, Suita, Osaka 564-8512, Japan."}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320727649797","@type":"Researcher","foaf:name":[{"@value":"Noritaka Mizuno"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, School of Engineering, University of Tokyo, 7-3-1 Hongo, Bunkyoku, Tokyo 113-8656, Japan."},{"@value":"Strategic Technology Research, Nippon Shokubai, 5-8 Nishi Otabi-cho, Suita, Osaka 564-8512, Japan."}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00368075"},{"@type":"EISSN","@value":"10959203"},{"@type":"PISSN","@value":"09317597"},{"@type":"EISSN","@value":"15222667"}],"prism:publicationName":[{"@value":"Science"}],"dc:publisher":[{"@value":"American Association for the Advancement of Science (AAAS)"}],"prism:publicationDate":"2003-05-09","prism:volume":"300","prism:number":"5621","prism:startingPage":"964","prism:endingPage":"966"},"reviewed":"false","url":[{"@id":"https://www.science.org/doi/pdf/10.1126/science.1083176"}],"createdAt":"2003-05-08","modifiedAt":"2024-12-12","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050001202624761984","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Enclosure of a Keggin-type heteropolyoxometalate into a tubular π-space via hydrogen bonds with a nonplanar Mo(V)-porphyrin complex forming a supramolecular assembly"}]},{"@id":"https://cir.nii.ac.jp/crid/1050292561213707520","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Polyoxocationic antimony oxide cluster with acidic 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Fe<sub>2</sub>O<sub>3</sub>as heterogeneous catalysts for selective oxidation with aqueous hydrogen peroxide"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641590217344","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Investigating the Transformations of Polyoxoanions Using Mass Spectrometry and Molecular Dynamics"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641806565632","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Remarkable enhancement of catalytic activity of a 2 : 1 complex between a non-planar Mo(v)–porphyrin and a ruthenium-substituted Keggin-type heteropolyoxometalate in catalytic oxidation of benzyl alcohols"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644040734080","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Efficient Oxidation of Alkane with O2 and H2 by Eu–Ti–Pt Catalytic System"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644040989952","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Structures and Sorption Properties of Ionic Crystals of Polyoxometalates with Macrocation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644041799168","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Inorganic Frameworks Made by Combining Paddle-wheel Diruthenium(II, III) Complexes and Polyoxometalate Clusters"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848654875833856","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Visible‐Light‐Responsive Multielectron Redox Catalysis of Lacunary Polyoxometalates Induced by Substrate Coordination to Their Lacuna"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658121696896","@type":"Article","resourceType":"学術雑誌論文(journal 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