{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320757704448.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1515/arh-2005-0001"}},{"identifier":{"@type":"URI","@value":"http://www.degruyter.com/view/j/arh.2005.15.issue-1/arh-2005-0001/arh-2005-0001.xml"}},{"identifier":{"@type":"URI","@value":"https://www.degruyter.com/document/doi/10.1515/arh-2005-0001/pdf"}}],"dc:title":[{"@value":"Capillary Break-up Rheometry of Low-Viscosity Elastic Fluids"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title>\n<jats:p>We investigate the dynamics of the capillary thinning and break-up process for low viscosity elastic fluids such as dilute polymer solutions. Standard measurements of the evolution of the midpoint diameter of the necking fluid filament are augmented by high speed digital video images of the break up dynamics. We show that the successful operation of a capillary thinning device is governed by three important time scales (which characterize the relative importance of inertial, viscous and elastic processes), and also by two important length scales (which specify the initial sample size and the total stretch imposed on the sample). By optimizing the ranges of these geometric parameters, we are able to measure characteristic time scales for tensile stress growth as small as 1 millisecond for a number of model dilute and semi-dilute solutions of polyethylene oxide (PEO) in water and glycerol. If the final aspect ratio of the sample is too small, or the total axial stretch is too great, measurements are limited, respectively, by inertial oscillations of the liquid bridge or by the development of the well-known beads-on-a-string morphology which disrupt the formation of a uniform necking filament. By considering the magnitudes of the natural time scales associated with viscous flow, elastic stress growth and inertial oscillations it is possible to construct an “operability diagram” characterizing successful operation of a capillary breakup extensional rheometer. For Newtonian fluids, viscosities greater than approximately 70 mPas are required; however for dilute solutions of high molecular weight polymer, the minimum viscosity is substantially lower due to the additional elastic stresses arising from molecular extension. For PEO of molecular weight 2 · 10<jats:sup>6</jats:sup> g/mol, it is possible to measure relaxation times of order 1 ms in dilute polymer solutions with zero-shear-rate viscosities on the order of 2 – 10 mPas.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670320757704448","@type":"Researcher","foaf:name":[{"@value":"Lucy E. Rodd"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320757704576","@type":"Researcher","foaf:name":[{"@value":"Timothy P. Scott"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320757704577","@type":"Researcher","foaf:name":[{"@value":"Justin J. Cooper-White"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320757704449","@type":"Researcher","foaf:name":[{"@value":"Gareth H. McKinley"}]}],"publication":{"publicationIdentifier":[{"@type":"EISSN","@value":"16178106"}],"prism:publicationName":[{"@value":"Applied Rheology"}],"dc:publisher":[{"@value":"Walter de Gruyter GmbH"}],"prism:publicationDate":"2005-02-01","prism:volume":"15","prism:number":"1","prism:startingPage":"12","prism:endingPage":"27"},"reviewed":"false","dc:rights":["http://creativecommons.org/licenses/by-nc-nd/3.0"],"url":[{"@id":"http://www.degruyter.com/view/j/arh.2005.15.issue-1/arh-2005-0001/arh-2005-0001.xml"},{"@id":"https://www.degruyter.com/document/doi/10.1515/arh-2005-0001/pdf"}],"createdAt":"2019-05-31","modifiedAt":"2021-04-21","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050026736298462592","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effects of Polydispersity and Concentration on Elastocapillary Thinning of Dilute Polymer 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Conductivity"}]},{"@id":"https://cir.nii.ac.jp/crid/1390013332639211776","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Comparison of Rheological Properties between DoS and Liquid Dropping Methods in Uniaxial Extensional Flow of Dilute Polymer Aqueous Solutions"},{"@language":"ja","@value":"希薄高分子水溶液の一軸伸長流れにおけるDoS法と液滴落下法の レオロジー特性の比較"},{"@value":"Comparison of rheological properties between DoS and liquid dropping methods in uniaxial extensional flow of dilute polymer aqueous solutions [Article in Japanese]"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680070964224","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Extensional Viscosity of Low Viscous Polymer Solutions Measured by Pressure Drops in Abrupt Contraction Channels"}]},{"@id":"https://cir.nii.ac.jp/crid/1390863783062096512","@type":"Article","resourceType":"学術雑誌論文(journal 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