{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320800807552.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/s0003-2670(01)96058-1"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0003267001960581?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0003267001960581?httpAccept=text/plain"}}],"dc:title":[{"@value":"A spectrophotometric study of the formation of mixed-ligand complexes of iron(III)-N-hydroxyethylethylene-diamine-N,N',N'-triacetate and thiocyanate, chloride, bromide or acetate"}],"description":[{"notation":[{"@value":"Abstract   The formation of mixed ligand complexes of Fe(HEEDTA) (H 2 O) with thiocyanate, chloride, bromide, and acetate(X), and their application to the spectrophotometric determination of iron(III) are described; 1:1:1 Fe:HEEDTA:X complexes are formed. The stability constants (log  K ) of the acetate, thiocyanate, and chloride mixed-ligaad complexes are 1.7, 1.2, and 0.2, respectively, at 25 °C. The thiocyanate complex (λmax, 425 nm) is suitable for the determination of iron(III) (1.6–8.0 μg ml −1 ). The molar absorptivity is 5.7·10 3  l mol −1  cm −1 , but the absorbance is very stable"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670320800807681","@type":"Researcher","foaf:name":[{"@value":"Katsumi Yamamoto"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320800807680","@type":"Researcher","foaf:name":[{"@value":"Kousaburo Ohasi"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00032670"}],"prism:publicationName":[{"@value":"Analytica Chimica Acta"}],"dc:publisher":[{"@value":"Elsevier BV"}],"prism:publicationDate":"1977-01","prism:volume":"88","prism:number":"1","prism:startingPage":"141","prism:endingPage":"146"},"reviewed":"false","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:S0003267001960581?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:S0003267001960581?httpAccept=text/plain"}],"createdAt":"2002-07-25","modifiedAt":"2019-05-06","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Spectroscopy","dc:title":"Spectroscopy"},{"@id":"https://cir.nii.ac.jp/all?q=Environmental%20Chemistry","dc:title":"Environmental Chemistry"},{"@id":"https://cir.nii.ac.jp/all?q=Biochemistry","dc:title":"Biochemistry"},{"@id":"https://cir.nii.ac.jp/all?q=Analytical%20Chemistry","dc:title":"Analytical Chemistry"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360283694077969536","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Studies on <i>N</i>1-Hydroxy-<i>N</i>1,<i>N</i>2-diarylbenzamidines as Metal Complexing Agents: Extraction-Photometric Determination of Iron(III) as Thiocyanato and Azido Mixed Ligand Complexes with <i>N</i>1-Hydroxy-<i>N</i>1,<i>N</i>2-diphenyl-<i>p</i>-toluamidinel(HDPTA)"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1016/s0003-2670(01)96058-1"},{"@type":"OPENAIRE","@value":"doi_dedup___::7dbb76d2a82264c659e143a3a3ac5b2e"},{"@type":"CROSSREF","@value":"10.1246/bcsj.52.595_references_DOI_6xaU6UzadMxcJQpXD5tI6EqKFzb"}]}