{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320855697792.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/ja060841r"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/ja060841r"}},{"identifier":{"@type":"PMID","@value":"16719439"}}],"dc:title":[{"@value":"Assembly State of Catalytic Modules as Chiral Switches in Asymmetric Strecker Amino Acid Synthesis"}],"description":[{"notation":[{"@value":"Self-assembled chiral polymetallic complexes often demonstrate novel properties as asymmetric catalysts. We report the three-dimensional structures of two such asymmetric catalysts (crystals A and B) for Strecker alpha,alpha-disubstituted amino acid synthesis. These complexes are constructed via assembly of the same chiral modules derived from d-glucose, but their assembly modes differ. The enantioselectivity in the Strecker reaction was dramatically switched, depending on which assembly mode was used: the catalyst generated in situ whose structure is represented by crystal B, or by crystal A. These findings provide insight into the functional importance of higher-order structures of an artificial catalyst."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670320855697920","@type":"Researcher","foaf:name":[{"@value":"Nobuki Kato"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city, Kagawa 769-2193, Japan, and JASCO International Co., Ltd., 1-11-10 Myojin-cho, Hachioji, Tokyo 192-0046, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320855697797","@type":"Researcher","foaf:name":[{"@value":"Tsuyoshi Mita"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city, Kagawa 769-2193, Japan, and JASCO International Co., Ltd., 1-11-10 Myojin-cho, Hachioji, Tokyo 192-0046, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320855697792","@type":"Researcher","foaf:name":[{"@value":"Motomu Kanai"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city, Kagawa 769-2193, Japan, and JASCO International Co., Ltd., 1-11-10 Myojin-cho, Hachioji, Tokyo 192-0046, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320855697921","@type":"Researcher","foaf:name":[{"@value":"Bruno Therrien"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city, Kagawa 769-2193, Japan, and JASCO International Co., Ltd., 1-11-10 Myojin-cho, Hachioji, Tokyo 192-0046, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320855697798","@type":"Researcher","foaf:name":[{"@value":"Masaki Kawano"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city, Kagawa 769-2193, Japan, and JASCO International Co., Ltd., 1-11-10 Myojin-cho, Hachioji, Tokyo 192-0046, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320855697794","@type":"Researcher","foaf:name":[{"@value":"Kentaro Yamaguchi"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city, Kagawa 769-2193, Japan, and JASCO International Co., Ltd., 1-11-10 Myojin-cho, Hachioji, Tokyo 192-0046, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320855697795","@type":"Researcher","foaf:name":[{"@value":"Hiroshi Danjo"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city, Kagawa 769-2193, Japan, and JASCO International Co., Ltd., 1-11-10 Myojin-cho, Hachioji, Tokyo 192-0046, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320855697922","@type":"Researcher","foaf:name":[{"@value":"Yoshihisa Sei"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city, Kagawa 769-2193, Japan, and JASCO International Co., Ltd., 1-11-10 Myojin-cho, Hachioji, Tokyo 192-0046, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320855697923","@type":"Researcher","foaf:name":[{"@value":"Akihiro Sato"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city, Kagawa 769-2193, Japan, and JASCO International Co., Ltd., 1-11-10 Myojin-cho, Hachioji, Tokyo 192-0046, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320855697796","@type":"Researcher","foaf:name":[{"@value":"Sanae Furusho"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city, Kagawa 769-2193, Japan, and JASCO International Co., Ltd., 1-11-10 Myojin-cho, Hachioji, Tokyo 192-0046, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320855697793","@type":"Researcher","foaf:name":[{"@value":"Masakatsu Shibasaki"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033, Japan, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city, Kagawa 769-2193, Japan, and JASCO International Co., Ltd., 1-11-10 Myojin-cho, Hachioji, Tokyo 192-0046, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00027863"},{"@type":"EISSN","@value":"15205126"}],"prism:publicationName":[{"@value":"Journal of the American Chemical Society"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2006-05-01","prism:volume":"128","prism:number":"21","prism:startingPage":"6768","prism:endingPage":"6769"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/ja060841r"}],"createdAt":"2006-05-24","modifiedAt":"2023-03-08","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Spectrometry,%20Mass,%20Electrospray%20Ionization","dc:title":"Spectrometry, Mass, Electrospray Ionization"},{"@id":"https://cir.nii.ac.jp/all?q=Molecular%20Structure","dc:title":"Molecular Structure"},{"@id":"https://cir.nii.ac.jp/all?q=X-Ray%20Diffraction","dc:title":"X-Ray Diffraction"},{"@id":"https://cir.nii.ac.jp/all?q=Chemistry,%20Organic","dc:title":"Chemistry, Organic"},{"@id":"https://cir.nii.ac.jp/all?q=Stereoisomerism","dc:title":"Stereoisomerism"},{"@id":"https://cir.nii.ac.jp/all?q=Amino%20Acids","dc:title":"Amino Acids"},{"@id":"https://cir.nii.ac.jp/all?q=Crystallization","dc:title":"Crystallization"},{"@id":"https://cir.nii.ac.jp/all?q=Catalysis","dc:title":"Catalysis"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360025429425903104","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Helical Sense Control of Metal–Peptide Torus Frameworks Leading to the Folding and Assembly of a Ag<sub>21</sub>L<sub>14</sub> Braided Peptide Nanotube"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691153255552","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Enantioselective alkylation of aldehydes using dialkylzincs catalyzed by simple chiral diols derived from naturally occurring monosaccharides"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708189384576","@type":"Article","resourceType":"学術雑誌論文(journal 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