{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320910377856.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/j.electacta.2007.03.042"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0013468607004161?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0013468607004161?httpAccept=text/plain"}}],"dc:title":[{"@value":"Seeded growth fabrication of Cu-on-Si electrodes for in situ ATR-SEIRAS applications"}],"description":[{"notation":[{"@value":"Abstract   A seeded-growth approach has been developed to fabricate a Cu nanoparticle film (simplified hereafter with nanofilm) on Si for electrochemical ATR surface-enhanced infrared absorption spectroscopy (ATR-SEIRAS). The approach comprises an initial activation of the reflecting plane of hemicylindrical Si prism by introducing a Cu seed layer in a CuSO 4 -HF solution and the subsequent electroless deposition of the Cu nanofilms from an electroless Cu plating bath. The as-deposited Cu nanofilm exhibited strong SEIRA effect for the CO probe and interfacial free H 2 O. ATR-SEIRAS was also applied to characterize the adsorbed geometries of pyridine at the Cu/electrolyte interface. Only vibrational bands assignable to the  A  1  symmetry modes were detected in the entire potential window investigated, suggestive of an end-on adsorption via the ring N-atom on a Cu electrode."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670320910377728","@type":"Researcher","foaf:name":[{"@value":"Hui-Feng Wang"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320910377856","@type":"Researcher","foaf:name":[{"@value":"Yan-Gang Yan"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320910377857","@type":"Researcher","foaf:name":[{"@value":"Sheng-Juan Huo"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320910377729","@type":"Researcher","foaf:name":[{"@value":"Wen-Bin Cai"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320910377730","@type":"Researcher","foaf:name":[{"@value":"Qun-Jie Xu"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320910377731","@type":"Researcher","foaf:name":[{"@value":"Masatoshi Osawa"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00134686"}],"prism:publicationName":[{"@value":"Electrochimica Acta"}],"dc:publisher":[{"@value":"Elsevier BV"}],"prism:publicationDate":"2007-05","prism:volume":"52","prism:number":"19","prism:startingPage":"5950","prism:endingPage":"5957"},"reviewed":"false","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:S0013468607004161?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:S0013468607004161?httpAccept=text/plain"}],"createdAt":"2007-03-21","modifiedAt":"2019-01-08","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002216615576960","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Tracking a Common Surface-Bound Intermediate during CO<sub>2</sub>-to-Fuels Catalysis"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1016/j.electacta.2007.03.042"},{"@type":"OPENAIRE","@value":"doi_dedup___::577eef058c8ae9ca7342dafd95c9f9dd"},{"@type":"CROSSREF","@value":"10.1021/acscentsci.6b00155_references_DOI_EV88dbMTdDdB5umtUWsKrgm9EtG"}]}