{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320971331200.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/0009-3084(87)90057-0"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:0009308487900570?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:0009308487900570?httpAccept=text/plain"}},{"identifier":{"@type":"NAID","@value":"80003618747"}}],"dc:title":[{"@value":"Biosynthetic pathway for C6-aldehydes formation from linolenic acid in green leaves"}],"description":[{"notation":[{"@value":"Abstract   ‘Green odour’ of green leaves consists of six volatile compounds of C6-aldehydes and C6-alcohols including leaf aldehyde, (2E)-hexenal, and leaf alcohol, (3Z)-hexenol. These volatile compounds are biosynthesized from linolenic and linoleic acids via their respective hydroperoxides in green leaves. Four enzymes catalyse this biosynthetic pathway. Among these, especially interesting enzymes are lipoxygenase and hydroperoxide lyase. The enzyme system is found in green leaves bound to the lamella membrane of chloroplasts. The lipoxygenase stereoselectively adds oxygen to unsaturated fatty acids having a (1Z, 4Z)-pentadiene moiety, such as linolenic and linoleic acids, to produce 13-(S)-hydroperoxides. The hydroperoxide lyase cleaves the bond between C-12 and C-13 of these hydroperoxides into C6-aldehydes. With regard to environmental effects on these enzymes, the activities change seasonally and appear to be closely related to temperature and to solar radiation received."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670320971331201","@type":"Researcher","foaf:name":[{"@value":"Akikazu Hatanaka"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320971331200","@type":"Researcher","foaf:name":[{"@value":"Tadahiko Kajiwara"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320971331072","@type":"Researcher","foaf:name":[{"@value":"Jiro Sekiya"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00093084"}],"prism:publicationName":[{"@value":"Chemistry and Physics of Lipids"}],"dc:publisher":[{"@value":"Elsevier BV"}],"prism:publicationDate":"1987-07","prism:volume":"44","prism:number":"2-4","prism:startingPage":"341","prism:endingPage":"361"},"reviewed":"false","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:0009308487900570?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:0009308487900570?httpAccept=text/plain"}],"createdAt":"2003-02-11","modifiedAt":"2020-03-12","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002219108537984","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Oxidative Decomposition of Methyl Linoleate by a Lipoxygenase Model Iron Complex Fe((pz)3BH)2"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233982743936","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Identification of (Z)-3:(E)-2-Hexenal Isomerases Essential to the Production of the Leaf Aldehyde in Plants"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565165992692096","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"α-Ketol linolenic acid (KODA) application affects endogenous abscisic acid, jasmonic acid and aromatic volatiles in grapes infected by a pathogen (Glomerella cingulata)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360584339770277120","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Retardation of ABA 8′-hydroxylase affects endogenous ABA, sugar metabolism, and aroma volatiles in grape berries"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679432902400","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy","isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Formation Mechanism of Grassy Odor Substance in Alfalfa Seedlings."}]},{"@id":"https://cir.nii.ac.jp/crid/1520854805311264128","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@value":"Molecular Cloning and Expression of Arabidopsis Fatty Acid Hydroperoxide Lyase"},{"@language":"ja-Kana","@value":"Molecular Cloning and Expression of Arabidopsis Fatty Acid Hydroperoxide Lyase"}]},{"@id":"https://cir.nii.ac.jp/crid/1572261551097355520","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Biological roles of monoterpene volatiles derived from rough lemon (Citrus jambhiri Lush) in citrus defense"}]},{"@id":"https://cir.nii.ac.jp/crid/2051996266922797824","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@value":"Purification and Properties of Fatty Acid Hydroperoxide Lyase from Green Bell Pepper Fruits : PROTEINS, ENZYMES AND METABOLISM : NATURAL PRODUCTS"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1016/0009-3084(87)90057-0"},{"@type":"CIA","@value":"80003618747"},{"@type":"OPENAIRE","@value":"doi_dedup___::e480c1853187cb1631dfbd5f8b6bbbc5"},{"@type":"CROSSREF","@value":"10.1074/jbc.m116.726687_references_DOI_C2hjkhSMJhhaH8J0H32rhnwdcll"},{"@type":"CROSSREF","@value":"10.17660/ejhs.2023/019_references_DOI_C2hjkhSMJhhaH8J0H32rhnwdcll"},{"@type":"CROSSREF","@value":"10.3136/fstr.8.347_references_DOI_C2hjkhSMJhhaH8J0H32rhnwdcll"},{"@type":"CROSSREF","@value":"10.1016/j.jplph.2016.01.009_references_DOI_C2hjkhSMJhhaH8J0H32rhnwdcll"},{"@type":"CROSSREF","@value":"10.1246/cl.1991.993_references_DOI_C2hjkhSMJhhaH8J0H32rhnwdcll"}]}