{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670320977346560.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/anie.201502308"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201502308"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201502308"}}],"dc:title":[{"@value":"Pd‐Catalyzed Regioselective Activation of <i>gem</i>‐Difluorinated Cyclopropanes: A Highly Efficient Approach to 2‐Fluorinated Allylic Scaffolds"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>An unprecedented Pd‐catalyzed regioselective activation of gem‐difluorinated cyclopropanes induced by CC bond cleavage is reported. It provides a general and efficient access to a variety of 2‐fluoroallylic amines, ethers, esters, and alkylation products in high Z‐selectivity, which are important skeletons in many biologically active molecules. In addition, the transformation represents the first general application of gem‐difluorinated cyclopropanes as reaction partners in transition‐metal‐catalyzed cross‐coupling reaction.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670320977346564","@type":"Researcher","foaf:name":[{"@value":"Jun Xu"}]},{"@id":"https://cir.nii.ac.jp/crid/1380016870196230273","@type":"Researcher","foaf:name":[{"@value":"Ebrahim‐Alkhalil Ahmed"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320977346560","@type":"Researcher","foaf:name":[{"@value":"Bin Xiao"}]},{"@id":"https://cir.nii.ac.jp/crid/1380016870196230272","@type":"Researcher","foaf:name":[{"@value":"Qian‐Qian Lu"}]},{"@id":"https://cir.nii.ac.jp/crid/1380016870196230275","@type":"Researcher","foaf:name":[{"@value":"Yun‐Long Wang"}]},{"@id":"https://cir.nii.ac.jp/crid/1380016870196230274","@type":"Researcher","foaf:name":[{"@value":"Chu‐Guo Yu"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670320977346562","@type":"Researcher","foaf:name":[{"@value":"Yao Fu"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14337851"},{"@type":"EISSN","@value":"15213773"}],"prism:publicationName":[{"@value":"Angewandte Chemie International Edition"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2015-06","prism:volume":"54","prism:number":"28","prism:startingPage":"8231","prism:endingPage":"8235"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201502308"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201502308"}],"createdAt":"2015-06-02","modifiedAt":"2023-10-16","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360286989471570176","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Transition‐Metal‐Mediated and ‐Catalyzed C−F Bond Activation by Fluorine Elimination"}]},{"@id":"https://cir.nii.ac.jp/crid/1360306904415375488","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"I\n                    <sub>2</sub>\n                    -mediated convenient ring-opening of simple\n                    <i>gem</i>\n                    -difluorocyclopropanes"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679564445824","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Silver-catalyzed Vinylic C–F Bond Activation: Synthesis of 2-Fluoroindoles from β,β-Difluoro-<i>o</i>-sulfonamidostyrenes"},{"@value":"Silver-catalyzed vinylic C-F bond activation : synthesis of 2-fluoroindoles from β,β-difluoro-o-sulfonamidostyrenes"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/anie.201502308"},{"@type":"CROSSREF","@value":"10.1002/anie.201805292_references_DOI_4cuSBv1G9JxldFcxJYmtVWOdP7y"},{"@type":"CROSSREF","@value":"10.1246/cl.160427_references_DOI_4cuSBv1G9JxldFcxJYmtVWOdP7y"},{"@type":"CROSSREF","@value":"10.1039/d5ob00128e_references_DOI_4cuSBv1G9JxldFcxJYmtVWOdP7y"}]}